(Z)-Ethyl 2-hydroxy­imino-2-(4-nitro­benz­yl)ethanoate

The title mol­ecule, C(11)H(10)N(2)O(6), has a Z conformation about the C=N bond of the oxime unit. There are significant twists from planarity throughout the mol­ecule, the most significant being between the hydroxy­imino and ester groups which are effectively orthogonal with an N—C—C—O(carbon­yl)...

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Detalles Bibliográficos
Autores principales: Caracelli, Ignez, Trindade, Antonio C., Moran, Paulo J. S., Hinoue, Luciana, Zukerman-Schpector, Julio, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980268/
https://www.ncbi.nlm.nih.gov/pubmed/21580028
http://dx.doi.org/10.1107/S1600536809052386
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author Caracelli, Ignez
Trindade, Antonio C.
Moran, Paulo J. S.
Hinoue, Luciana
Zukerman-Schpector, Julio
Tiekink, Edward R. T.
author_facet Caracelli, Ignez
Trindade, Antonio C.
Moran, Paulo J. S.
Hinoue, Luciana
Zukerman-Schpector, Julio
Tiekink, Edward R. T.
author_sort Caracelli, Ignez
collection PubMed
description The title mol­ecule, C(11)H(10)N(2)O(6), has a Z conformation about the C=N bond of the oxime unit. There are significant twists from planarity throughout the mol­ecule, the most significant being between the hydroxy­imino and ester groups which are effectively orthogonal with an N—C—C—O(carbon­yl) torsion angle of 91.4 (2)°. The crystal packing features oxime–benzoyl O—H⋯O contacts that lead to chains along [010] and C—H⋯O interactions also occur.
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spelling pubmed-29802682010-12-30 (Z)-Ethyl 2-hydroxy­imino-2-(4-nitro­benz­yl)ethanoate Caracelli, Ignez Trindade, Antonio C. Moran, Paulo J. S. Hinoue, Luciana Zukerman-Schpector, Julio Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(11)H(10)N(2)O(6), has a Z conformation about the C=N bond of the oxime unit. There are significant twists from planarity throughout the mol­ecule, the most significant being between the hydroxy­imino and ester groups which are effectively orthogonal with an N—C—C—O(carbon­yl) torsion angle of 91.4 (2)°. The crystal packing features oxime–benzoyl O—H⋯O contacts that lead to chains along [010] and C—H⋯O interactions also occur. International Union of Crystallography 2009-12-16 /pmc/articles/PMC2980268/ /pubmed/21580028 http://dx.doi.org/10.1107/S1600536809052386 Text en © Caracelli et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Caracelli, Ignez
Trindade, Antonio C.
Moran, Paulo J. S.
Hinoue, Luciana
Zukerman-Schpector, Julio
Tiekink, Edward R. T.
(Z)-Ethyl 2-hydroxy­imino-2-(4-nitro­benz­yl)ethanoate
title (Z)-Ethyl 2-hydroxy­imino-2-(4-nitro­benz­yl)ethanoate
title_full (Z)-Ethyl 2-hydroxy­imino-2-(4-nitro­benz­yl)ethanoate
title_fullStr (Z)-Ethyl 2-hydroxy­imino-2-(4-nitro­benz­yl)ethanoate
title_full_unstemmed (Z)-Ethyl 2-hydroxy­imino-2-(4-nitro­benz­yl)ethanoate
title_short (Z)-Ethyl 2-hydroxy­imino-2-(4-nitro­benz­yl)ethanoate
title_sort (z)-ethyl 2-hydroxy­imino-2-(4-nitro­benz­yl)ethanoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980268/
https://www.ncbi.nlm.nih.gov/pubmed/21580028
http://dx.doi.org/10.1107/S1600536809052386
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