Cargando…

7-Bromo-1-(4-chloro­phenyl­sulfan­yl)-2-phenyl­naphtho[2,1-b]furan

In the title compound, C(24)H(14)BrClOS, the S-bound 4-chloro­phenyl ring is nearly perpendicular to the plane of the naphthofuran fragment [dihedral angle = 83.34 (3)°] and the phenyl ring in the 2-position is rotated out of the naphthofuran plane by a dihedral angle of 15.23 (5)°. The crystal stru...

Descripción completa

Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Kim, Byung Ki, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980269/
https://www.ncbi.nlm.nih.gov/pubmed/21580059
http://dx.doi.org/10.1107/S1600536809052945
_version_ 1782191618288254976
author Choi, Hong Dae
Seo, Pil Ja
Kim, Byung Ki
Son, Byeng Wha
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Kim, Byung Ki
Son, Byeng Wha
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description In the title compound, C(24)H(14)BrClOS, the S-bound 4-chloro­phenyl ring is nearly perpendicular to the plane of the naphthofuran fragment [dihedral angle = 83.34 (3)°] and the phenyl ring in the 2-position is rotated out of the naphthofuran plane by a dihedral angle of 15.23 (5)°. The crystal structure is stabilized by aromatic π–π inter­actions between the furan and the central benzene rings of the neighbouring naphthofuran fragments, and between the outer benzene rings of the neighbouring naphthofuran fragments; the centroid–centroid distances within the stack are 3.879 (2) and 3.857 (2) Å. In addition, inter­molecular C—Cl⋯π inter­actions [3.505 (2) Å] between the Cl atom and the 2-phenyl ring are present.
format Text
id pubmed-2980269
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29802692010-12-30 7-Bromo-1-(4-chloro­phenyl­sulfan­yl)-2-phenyl­naphtho[2,1-b]furan Choi, Hong Dae Seo, Pil Ja Kim, Byung Ki Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(14)BrClOS, the S-bound 4-chloro­phenyl ring is nearly perpendicular to the plane of the naphthofuran fragment [dihedral angle = 83.34 (3)°] and the phenyl ring in the 2-position is rotated out of the naphthofuran plane by a dihedral angle of 15.23 (5)°. The crystal structure is stabilized by aromatic π–π inter­actions between the furan and the central benzene rings of the neighbouring naphthofuran fragments, and between the outer benzene rings of the neighbouring naphthofuran fragments; the centroid–centroid distances within the stack are 3.879 (2) and 3.857 (2) Å. In addition, inter­molecular C—Cl⋯π inter­actions [3.505 (2) Å] between the Cl atom and the 2-phenyl ring are present. International Union of Crystallography 2009-12-16 /pmc/articles/PMC2980269/ /pubmed/21580059 http://dx.doi.org/10.1107/S1600536809052945 Text en © Choi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Kim, Byung Ki
Son, Byeng Wha
Lee, Uk
7-Bromo-1-(4-chloro­phenyl­sulfan­yl)-2-phenyl­naphtho[2,1-b]furan
title 7-Bromo-1-(4-chloro­phenyl­sulfan­yl)-2-phenyl­naphtho[2,1-b]furan
title_full 7-Bromo-1-(4-chloro­phenyl­sulfan­yl)-2-phenyl­naphtho[2,1-b]furan
title_fullStr 7-Bromo-1-(4-chloro­phenyl­sulfan­yl)-2-phenyl­naphtho[2,1-b]furan
title_full_unstemmed 7-Bromo-1-(4-chloro­phenyl­sulfan­yl)-2-phenyl­naphtho[2,1-b]furan
title_short 7-Bromo-1-(4-chloro­phenyl­sulfan­yl)-2-phenyl­naphtho[2,1-b]furan
title_sort 7-bromo-1-(4-chloro­phenyl­sulfan­yl)-2-phenyl­naphtho[2,1-b]furan
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980269/
https://www.ncbi.nlm.nih.gov/pubmed/21580059
http://dx.doi.org/10.1107/S1600536809052945
work_keys_str_mv AT choihongdae 7bromo14chlorophenylsulfanyl2phenylnaphtho21bfuran
AT seopilja 7bromo14chlorophenylsulfanyl2phenylnaphtho21bfuran
AT kimbyungki 7bromo14chlorophenylsulfanyl2phenylnaphtho21bfuran
AT sonbyengwha 7bromo14chlorophenylsulfanyl2phenylnaphtho21bfuran
AT leeuk 7bromo14chlorophenylsulfanyl2phenylnaphtho21bfuran