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7-Chloro-4-[(E)-N′-(4-fluorobenzylidene)hydrazinyl]quinoline monohydrate
The molecule of the title hydrate, C(16)H(11)ClFN(3)·H(2)O, is slightly twisted, as indicated by the dihedral angle of 9.55 (10)° formed between the quinoline ring system and the benzene ring. The conformation about the C=N double bond is E, and the amine-H atom is oriented towards the quinoline re...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980273/ https://www.ncbi.nlm.nih.gov/pubmed/21580042 http://dx.doi.org/10.1107/S1600536809053367 |
Sumario: | The molecule of the title hydrate, C(16)H(11)ClFN(3)·H(2)O, is slightly twisted, as indicated by the dihedral angle of 9.55 (10)° formed between the quinoline ring system and the benzene ring. The conformation about the C=N double bond is E, and the amine-H atom is oriented towards the quinoline residue. In the crystal structure, the water molecule accepts an N—H⋯O and makes two O—H⋯N(quinoline) hydrogen bonds, generating a two-dimensional array in the ab plane, which is further stabilized by C—H⋯O interactions. The most significant contacts between layers are of the type C—H⋯F. |
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