1-(12-Azido-n-dodec­yl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetra­hydro-1H-1,5-benzodiazepin-3-yl)meth­yl]-1H-1,2,3-triazole

The reaction of 1,5-dibenzyl-3-propargyl-1,5-benzodiazepine-2,4-dione with 1,12-diazido-n-dodecane in the presence of catalysts leads to the formation of the title compound, C(38)H(46)N(8)O(2). The seven-membered diazepinyl ring adopts a boat conformation with the azido­dodecyl­triazolylmethyl-beari...

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Autores principales: Jabli, Hind, Ouazzani Chahdi, F., Saffon, Natalie, Essassi, El Mokhtar, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980277/
https://www.ncbi.nlm.nih.gov/pubmed/21580114
http://dx.doi.org/10.1107/S1600536809054464
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author Jabli, Hind
Ouazzani Chahdi, F.
Saffon, Natalie
Essassi, El Mokhtar
Ng, Seik Weng
author_facet Jabli, Hind
Ouazzani Chahdi, F.
Saffon, Natalie
Essassi, El Mokhtar
Ng, Seik Weng
author_sort Jabli, Hind
collection PubMed
description The reaction of 1,5-dibenzyl-3-propargyl-1,5-benzodiazepine-2,4-dione with 1,12-diazido-n-dodecane in the presence of catalysts leads to the formation of the title compound, C(38)H(46)N(8)O(2). The seven-membered diazepinyl ring adopts a boat conformation with the azido­dodecyl­triazolylmethyl-bearing C atom as the prow and the fused-ring C atoms as the stern. The octyltriazolylmethyl substituent occupies an axial position.
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spelling pubmed-29802772010-12-30 1-(12-Azido-n-dodec­yl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetra­hydro-1H-1,5-benzodiazepin-3-yl)meth­yl]-1H-1,2,3-triazole Jabli, Hind Ouazzani Chahdi, F. Saffon, Natalie Essassi, El Mokhtar Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The reaction of 1,5-dibenzyl-3-propargyl-1,5-benzodiazepine-2,4-dione with 1,12-diazido-n-dodecane in the presence of catalysts leads to the formation of the title compound, C(38)H(46)N(8)O(2). The seven-membered diazepinyl ring adopts a boat conformation with the azido­dodecyl­triazolylmethyl-bearing C atom as the prow and the fused-ring C atoms as the stern. The octyltriazolylmethyl substituent occupies an axial position. International Union of Crystallography 2009-12-24 /pmc/articles/PMC2980277/ /pubmed/21580114 http://dx.doi.org/10.1107/S1600536809054464 Text en © Jabli et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jabli, Hind
Ouazzani Chahdi, F.
Saffon, Natalie
Essassi, El Mokhtar
Ng, Seik Weng
1-(12-Azido-n-dodec­yl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetra­hydro-1H-1,5-benzodiazepin-3-yl)meth­yl]-1H-1,2,3-triazole
title 1-(12-Azido-n-dodec­yl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetra­hydro-1H-1,5-benzodiazepin-3-yl)meth­yl]-1H-1,2,3-triazole
title_full 1-(12-Azido-n-dodec­yl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetra­hydro-1H-1,5-benzodiazepin-3-yl)meth­yl]-1H-1,2,3-triazole
title_fullStr 1-(12-Azido-n-dodec­yl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetra­hydro-1H-1,5-benzodiazepin-3-yl)meth­yl]-1H-1,2,3-triazole
title_full_unstemmed 1-(12-Azido-n-dodec­yl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetra­hydro-1H-1,5-benzodiazepin-3-yl)meth­yl]-1H-1,2,3-triazole
title_short 1-(12-Azido-n-dodec­yl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetra­hydro-1H-1,5-benzodiazepin-3-yl)meth­yl]-1H-1,2,3-triazole
title_sort 1-(12-azido-n-dodec­yl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetra­hydro-1h-1,5-benzodiazepin-3-yl)meth­yl]-1h-1,2,3-triazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980277/
https://www.ncbi.nlm.nih.gov/pubmed/21580114
http://dx.doi.org/10.1107/S1600536809054464
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