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[N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P′]dichloridoplatinum(II)

The Pt(II) atom in the title compound, [PtCl(2)(C(27)H(27)NP(2))], has a highly distorted square-planar geometry, as evidenced by the P—Pt—P bite angle [72.4 (1)°]. The strain in the complex is further illustrated by the distorted tetra­hedral angles of the P atoms, which range between 93.5 (1) and...

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Detalles Bibliográficos
Autores principales: Cloete, Nicoline, Visser, Hendrik G., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980280/
https://www.ncbi.nlm.nih.gov/pubmed/21579949
http://dx.doi.org/10.1107/S160053680905301X
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author Cloete, Nicoline
Visser, Hendrik G.
Roodt, Andreas
author_facet Cloete, Nicoline
Visser, Hendrik G.
Roodt, Andreas
author_sort Cloete, Nicoline
collection PubMed
description The Pt(II) atom in the title compound, [PtCl(2)(C(27)H(27)NP(2))], has a highly distorted square-planar geometry, as evidenced by the P—Pt—P bite angle [72.4 (1)°]. The strain in the complex is further illustrated by the distorted tetra­hedral angles of the P atoms, which range between 93.5 (1) and 122.2 (1)°. It is of inter­est to note that the N atom has to adopt an almost planar geometry with the two P atoms and the C atom attached to it [it is displaced by 0.093 (2) Å from the CP(2) plane] in order to accommodate the steric bulk of the phenyl groups and the alkyl group of the ligand coordinated to the Pt(II) centre. The mol­ecules pack in horizontal rows across the bc plane. C—H⋯Cl hydrogen bonds stabilize the crystal packing.
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spelling pubmed-29802802010-12-30 [N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P′]dichloridoplatinum(II) Cloete, Nicoline Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pt(II) atom in the title compound, [PtCl(2)(C(27)H(27)NP(2))], has a highly distorted square-planar geometry, as evidenced by the P—Pt—P bite angle [72.4 (1)°]. The strain in the complex is further illustrated by the distorted tetra­hedral angles of the P atoms, which range between 93.5 (1) and 122.2 (1)°. It is of inter­est to note that the N atom has to adopt an almost planar geometry with the two P atoms and the C atom attached to it [it is displaced by 0.093 (2) Å from the CP(2) plane] in order to accommodate the steric bulk of the phenyl groups and the alkyl group of the ligand coordinated to the Pt(II) centre. The mol­ecules pack in horizontal rows across the bc plane. C—H⋯Cl hydrogen bonds stabilize the crystal packing. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980280/ /pubmed/21579949 http://dx.doi.org/10.1107/S160053680905301X Text en © Cloete et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cloete, Nicoline
Visser, Hendrik G.
Roodt, Andreas
[N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P′]dichloridoplatinum(II)
title [N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P′]dichloridoplatinum(II)
title_full [N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P′]dichloridoplatinum(II)
title_fullStr [N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P′]dichloridoplatinum(II)
title_full_unstemmed [N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P′]dichloridoplatinum(II)
title_short [N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P′]dichloridoplatinum(II)
title_sort [n,n-bis(diphenyl­phosphino)propyl­amine-κ(2) p,p′]dichloridoplatinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980280/
https://www.ncbi.nlm.nih.gov/pubmed/21579949
http://dx.doi.org/10.1107/S160053680905301X
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