6-Formyl-2-naphthyl cis-1,5,7-trimethyl-2,4-dioxo-3-aza­bicyclo­[3.3.1]nonane-7-carboxyl­ate

In the title compound, C(23)H(23)NO(5), the C(5)N ring adopts an envelope conformation with a C atom as the flap, whilst the saturated C(6) ring fused to it adopts a chair conformation. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops.

Detalles Bibliográficos
Autores principales: Xu, Sheng-guang, Wang, Chun-hua, Liu, Jun-shen, Liu, Xi-guang, Li, Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980281/
https://www.ncbi.nlm.nih.gov/pubmed/21580126
http://dx.doi.org/10.1107/S1600536809054786
_version_ 1782191621526257664
author Xu, Sheng-guang
Wang, Chun-hua
Liu, Jun-shen
Liu, Xi-guang
Li, Long
author_facet Xu, Sheng-guang
Wang, Chun-hua
Liu, Jun-shen
Liu, Xi-guang
Li, Long
author_sort Xu, Sheng-guang
collection PubMed
description In the title compound, C(23)H(23)NO(5), the C(5)N ring adopts an envelope conformation with a C atom as the flap, whilst the saturated C(6) ring fused to it adopts a chair conformation. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops.
format Text
id pubmed-2980281
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29802812010-12-30 6-Formyl-2-naphthyl cis-1,5,7-trimethyl-2,4-dioxo-3-aza­bicyclo­[3.3.1]nonane-7-carboxyl­ate Xu, Sheng-guang Wang, Chun-hua Liu, Jun-shen Liu, Xi-guang Li, Long Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(23)NO(5), the C(5)N ring adopts an envelope conformation with a C atom as the flap, whilst the saturated C(6) ring fused to it adopts a chair conformation. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. International Union of Crystallography 2009-12-24 /pmc/articles/PMC2980281/ /pubmed/21580126 http://dx.doi.org/10.1107/S1600536809054786 Text en © Xu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xu, Sheng-guang
Wang, Chun-hua
Liu, Jun-shen
Liu, Xi-guang
Li, Long
6-Formyl-2-naphthyl cis-1,5,7-trimethyl-2,4-dioxo-3-aza­bicyclo­[3.3.1]nonane-7-carboxyl­ate
title 6-Formyl-2-naphthyl cis-1,5,7-trimethyl-2,4-dioxo-3-aza­bicyclo­[3.3.1]nonane-7-carboxyl­ate
title_full 6-Formyl-2-naphthyl cis-1,5,7-trimethyl-2,4-dioxo-3-aza­bicyclo­[3.3.1]nonane-7-carboxyl­ate
title_fullStr 6-Formyl-2-naphthyl cis-1,5,7-trimethyl-2,4-dioxo-3-aza­bicyclo­[3.3.1]nonane-7-carboxyl­ate
title_full_unstemmed 6-Formyl-2-naphthyl cis-1,5,7-trimethyl-2,4-dioxo-3-aza­bicyclo­[3.3.1]nonane-7-carboxyl­ate
title_short 6-Formyl-2-naphthyl cis-1,5,7-trimethyl-2,4-dioxo-3-aza­bicyclo­[3.3.1]nonane-7-carboxyl­ate
title_sort 6-formyl-2-naphthyl cis-1,5,7-trimethyl-2,4-dioxo-3-aza­bicyclo­[3.3.1]nonane-7-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980281/
https://www.ncbi.nlm.nih.gov/pubmed/21580126
http://dx.doi.org/10.1107/S1600536809054786
work_keys_str_mv AT xushengguang 6formyl2naphthylcis157trimethyl24dioxo3azabicyclo331nonane7carboxylate
AT wangchunhua 6formyl2naphthylcis157trimethyl24dioxo3azabicyclo331nonane7carboxylate
AT liujunshen 6formyl2naphthylcis157trimethyl24dioxo3azabicyclo331nonane7carboxylate
AT liuxiguang 6formyl2naphthylcis157trimethyl24dioxo3azabicyclo331nonane7carboxylate
AT lilong 6formyl2naphthylcis157trimethyl24dioxo3azabicyclo331nonane7carboxylate

Ejemplares similares