Formation of epoxide-amine oligo-adducts as OH-functionalized initiators for the ring-opening polymerization of ε-caprolactone

Epoxide-amine oligo-adducts were synthesized via a one-pot microwave assisted heterogeneous catalytic transfer hydrogenation. Accordingly, 4-nitroanisole was reduced under microwave conditions to give 4-aminoanisole which reacted immediately with the diglycidyl ether of bisphenol A in an addition po...

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Autores principales: Theis, Julia, Ritter, Helmut
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2010
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2981823/
https://www.ncbi.nlm.nih.gov/pubmed/21085507
http://dx.doi.org/10.3762/bjoc.6.105
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author Theis, Julia
Ritter, Helmut
author_facet Theis, Julia
Ritter, Helmut
author_sort Theis, Julia
collection PubMed
description Epoxide-amine oligo-adducts were synthesized via a one-pot microwave assisted heterogeneous catalytic transfer hydrogenation. Accordingly, 4-nitroanisole was reduced under microwave conditions to give 4-aminoanisole which reacted immediately with the diglycidyl ether of bisphenol A in an addition polymerization reaction to yield oligo(amino alcohol)s. The hydroxy groups of the new formed oligomers were used as the initiator for the ring-opening polymerization of ε-caprolactone to produce a graft copolymer.
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spelling pubmed-29818232010-11-17 Formation of epoxide-amine oligo-adducts as OH-functionalized initiators for the ring-opening polymerization of ε-caprolactone Theis, Julia Ritter, Helmut Beilstein J Org Chem Full Research Paper Epoxide-amine oligo-adducts were synthesized via a one-pot microwave assisted heterogeneous catalytic transfer hydrogenation. Accordingly, 4-nitroanisole was reduced under microwave conditions to give 4-aminoanisole which reacted immediately with the diglycidyl ether of bisphenol A in an addition polymerization reaction to yield oligo(amino alcohol)s. The hydroxy groups of the new formed oligomers were used as the initiator for the ring-opening polymerization of ε-caprolactone to produce a graft copolymer. Beilstein-Institut 2010-10-01 /pmc/articles/PMC2981823/ /pubmed/21085507 http://dx.doi.org/10.3762/bjoc.6.105 Text en Copyright © 2010, Theis and Ritter https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Theis, Julia
Ritter, Helmut
Formation of epoxide-amine oligo-adducts as OH-functionalized initiators for the ring-opening polymerization of ε-caprolactone
title Formation of epoxide-amine oligo-adducts as OH-functionalized initiators for the ring-opening polymerization of ε-caprolactone
title_full Formation of epoxide-amine oligo-adducts as OH-functionalized initiators for the ring-opening polymerization of ε-caprolactone
title_fullStr Formation of epoxide-amine oligo-adducts as OH-functionalized initiators for the ring-opening polymerization of ε-caprolactone
title_full_unstemmed Formation of epoxide-amine oligo-adducts as OH-functionalized initiators for the ring-opening polymerization of ε-caprolactone
title_short Formation of epoxide-amine oligo-adducts as OH-functionalized initiators for the ring-opening polymerization of ε-caprolactone
title_sort formation of epoxide-amine oligo-adducts as oh-functionalized initiators for the ring-opening polymerization of ε-caprolactone
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2981823/
https://www.ncbi.nlm.nih.gov/pubmed/21085507
http://dx.doi.org/10.3762/bjoc.6.105
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