Tetra­imidazolium hexa-μ(4)-oxido-dodeca-μ(2)-oxido-dodeca­oxidohexa­arsenate(III)hexa­molybdenum(VI)cuprate(II)

The title compound, (C(3)H(5)N(2))(4)[As(6)CuMo(6)O(30)], is made up of a centrosymmetric anionic cluster and four imidazolium cations. In the cluster, the central Cu(II) atom is six-coordinated and lies on an inversion center. Adjacent clusters are linked via N—H⋯O hydrogen bonds between the imidaz...

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Detalles Bibliográficos
Autores principales: Liu, Meiduo, Su, Zhanhua, Shang, Yongchen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983113/
https://www.ncbi.nlm.nih.gov/pubmed/21587445
http://dx.doi.org/10.1107/S1600536810037414
Descripción
Sumario:The title compound, (C(3)H(5)N(2))(4)[As(6)CuMo(6)O(30)], is made up of a centrosymmetric anionic cluster and four imidazolium cations. In the cluster, the central Cu(II) atom is six-coordinated and lies on an inversion center. Adjacent clusters are linked via N—H⋯O hydrogen bonds between the imidazole cations and polyoxidoanions into a three-dimensional supra­molecular architecture.

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