4-Methyl-9-[(4-methyl­phen­yl)sulfon­yl]thio­pyrano[3,4-b]indole-3(9H)-thione

The title compound, C(19)H(15)NO(2)S(3), is the first example of a dithia analogue of pyrano[3,4-b]indolone. The almost planar thio­pyrano­indole­thione ring system (r.m.s. deviation for all non-H atoms = 0.030 Å) makes a dihedral angle of 80.70 (8)° with the p-tolyl ring. In the crystal, mol­ecules...

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Detalles Bibliográficos
Autores principales: Dassonneville, Benjamin, Schollmeyer, Dieter, Witulski, Bernhard, Detert, Heiner
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983115/
https://www.ncbi.nlm.nih.gov/pubmed/21587636
http://dx.doi.org/10.1107/S1600536810038201
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author Dassonneville, Benjamin
Schollmeyer, Dieter
Witulski, Bernhard
Detert, Heiner
author_facet Dassonneville, Benjamin
Schollmeyer, Dieter
Witulski, Bernhard
Detert, Heiner
author_sort Dassonneville, Benjamin
collection PubMed
description The title compound, C(19)H(15)NO(2)S(3), is the first example of a dithia analogue of pyrano[3,4-b]indolone. The almost planar thio­pyrano­indole­thione ring system (r.m.s. deviation for all non-H atoms = 0.030 Å) makes a dihedral angle of 80.70 (8)° with the p-tolyl ring. In the crystal, mol­ecules are connected via C—H⋯O hydrogen bonds into two chains along the b axis. These chains are connected via π–π inter­actions between symmetry-related thio­pyrano­indole­thione ring systems [centroid–centroid distance = 3.588 (1) Å].
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spelling pubmed-29831152010-12-30 4-Methyl-9-[(4-methyl­phen­yl)sulfon­yl]thio­pyrano[3,4-b]indole-3(9H)-thione Dassonneville, Benjamin Schollmeyer, Dieter Witulski, Bernhard Detert, Heiner Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(15)NO(2)S(3), is the first example of a dithia analogue of pyrano[3,4-b]indolone. The almost planar thio­pyrano­indole­thione ring system (r.m.s. deviation for all non-H atoms = 0.030 Å) makes a dihedral angle of 80.70 (8)° with the p-tolyl ring. In the crystal, mol­ecules are connected via C—H⋯O hydrogen bonds into two chains along the b axis. These chains are connected via π–π inter­actions between symmetry-related thio­pyrano­indole­thione ring systems [centroid–centroid distance = 3.588 (1) Å]. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983115/ /pubmed/21587636 http://dx.doi.org/10.1107/S1600536810038201 Text en © Dassonneville et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dassonneville, Benjamin
Schollmeyer, Dieter
Witulski, Bernhard
Detert, Heiner
4-Methyl-9-[(4-methyl­phen­yl)sulfon­yl]thio­pyrano[3,4-b]indole-3(9H)-thione
title 4-Methyl-9-[(4-methyl­phen­yl)sulfon­yl]thio­pyrano[3,4-b]indole-3(9H)-thione
title_full 4-Methyl-9-[(4-methyl­phen­yl)sulfon­yl]thio­pyrano[3,4-b]indole-3(9H)-thione
title_fullStr 4-Methyl-9-[(4-methyl­phen­yl)sulfon­yl]thio­pyrano[3,4-b]indole-3(9H)-thione
title_full_unstemmed 4-Methyl-9-[(4-methyl­phen­yl)sulfon­yl]thio­pyrano[3,4-b]indole-3(9H)-thione
title_short 4-Methyl-9-[(4-methyl­phen­yl)sulfon­yl]thio­pyrano[3,4-b]indole-3(9H)-thione
title_sort 4-methyl-9-[(4-methyl­phen­yl)sulfon­yl]thio­pyrano[3,4-b]indole-3(9h)-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983115/
https://www.ncbi.nlm.nih.gov/pubmed/21587636
http://dx.doi.org/10.1107/S1600536810038201
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AT detertheiner 4methyl94methylphenylsulfonylthiopyrano34bindole39hthione

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