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Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6) O (1):O (1′):O (3):O (3′):O (5):O (5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(2) O:O′)trimagnesium(II)]
The title complex, [Mg(3)(CHO(2))(3)(C(9)H(3)O(6))(C(3)H(7)NO)(3)](n), exhibits a two-dimensional structure parallel to (001), which is built up from the Mg(II) atoms and bridging carboxylate ligands (3 symmetry). The Mg(II) atom is six-coordinated by one O atom from a dimethylformamide molecule...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983117/ https://www.ncbi.nlm.nih.gov/pubmed/21587431 http://dx.doi.org/10.1107/S1600536810035907 |
Sumario: | The title complex, [Mg(3)(CHO(2))(3)(C(9)H(3)O(6))(C(3)H(7)NO)(3)](n), exhibits a two-dimensional structure parallel to (001), which is built up from the Mg(II) atoms and bridging carboxylate ligands (3 symmetry). The Mg(II) atom is six-coordinated by one O atom from a dimethylformamide molecule, two O atoms from two μ(6)-benzene-1,3,5-tricarboxylate ligands and three O atoms from three μ(3)-formate ligands in a distorted octahedral geometry. |
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