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Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6) O (1):O (1′):O (3):O (3′):O (5):O (5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(2) O:O′)trimagnesium(II)]
The title complex, [Mg(3)(CHO(2))(3)(C(9)H(3)O(6))(C(3)H(7)NO)(3)](n), exhibits a two-dimensional structure parallel to (001), which is built up from the Mg(II) atoms and bridging carboxylate ligands (3 symmetry). The Mg(II) atom is six-coordinated by one O atom from a dimethylformamide molecule...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983117/ https://www.ncbi.nlm.nih.gov/pubmed/21587431 http://dx.doi.org/10.1107/S1600536810035907 |
| _version_ | 1782191804481798144 |
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| author | Yeh, Chun-Ting Liu, Hsin-Kuan Lin, Chia-Jing Lin, Chia-Her |
| author_facet | Yeh, Chun-Ting Liu, Hsin-Kuan Lin, Chia-Jing Lin, Chia-Her |
| author_sort | Yeh, Chun-Ting |
| collection | PubMed |
| description | The title complex, [Mg(3)(CHO(2))(3)(C(9)H(3)O(6))(C(3)H(7)NO)(3)](n), exhibits a two-dimensional structure parallel to (001), which is built up from the Mg(II) atoms and bridging carboxylate ligands (3 symmetry). The Mg(II) atom is six-coordinated by one O atom from a dimethylformamide molecule, two O atoms from two μ(6)-benzene-1,3,5-tricarboxylate ligands and three O atoms from three μ(3)-formate ligands in a distorted octahedral geometry. |
| format | Text |
| id | pubmed-2983117 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29831172010-12-30 Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6) O (1):O (1′):O (3):O (3′):O (5):O (5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(2) O:O′)trimagnesium(II)] Yeh, Chun-Ting Liu, Hsin-Kuan Lin, Chia-Jing Lin, Chia-Her Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Mg(3)(CHO(2))(3)(C(9)H(3)O(6))(C(3)H(7)NO)(3)](n), exhibits a two-dimensional structure parallel to (001), which is built up from the Mg(II) atoms and bridging carboxylate ligands (3 symmetry). The Mg(II) atom is six-coordinated by one O atom from a dimethylformamide molecule, two O atoms from two μ(6)-benzene-1,3,5-tricarboxylate ligands and three O atoms from three μ(3)-formate ligands in a distorted octahedral geometry. International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983117/ /pubmed/21587431 http://dx.doi.org/10.1107/S1600536810035907 Text en © Yeh et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Yeh, Chun-Ting Liu, Hsin-Kuan Lin, Chia-Jing Lin, Chia-Her Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6) O (1):O (1′):O (3):O (3′):O (5):O (5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(2) O:O′)trimagnesium(II)] |
| title | Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6)
O
(1):O
(1′):O
(3):O
(3′):O
(5):O
(5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(2)
O:O′)trimagnesium(II)] |
| title_full | Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6)
O
(1):O
(1′):O
(3):O
(3′):O
(5):O
(5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(2)
O:O′)trimagnesium(II)] |
| title_fullStr | Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6)
O
(1):O
(1′):O
(3):O
(3′):O
(5):O
(5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(2)
O:O′)trimagnesium(II)] |
| title_full_unstemmed | Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6)
O
(1):O
(1′):O
(3):O
(3′):O
(5):O
(5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(2)
O:O′)trimagnesium(II)] |
| title_short | Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6)
O
(1):O
(1′):O
(3):O
(3′):O
(5):O
(5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(2)
O:O′)trimagnesium(II)] |
| title_sort | poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6)
o
(1):o
(1′):o
(3):o
(3′):o
(5):o
(5′))tris(n,n-dimethylformamide-κo)tris(μ(3)-formato-κ(2)
o:o′)trimagnesium(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983117/ https://www.ncbi.nlm.nih.gov/pubmed/21587431 http://dx.doi.org/10.1107/S1600536810035907 |
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