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Poly[dichloridobis[μ-1-(4-pyridyl­meth­yl)-1,2,4-triazole]cadmium(II)]

In the title coordination polymer, [CdCl(2)(C(8)H(8)N(4))(2)](n), the Cd(II) atom, lying on an inversion center, is coordinated by two Cl atoms and two triazole N atoms and two pyridyl N atoms from four 1-(4-pyridyl­meth­yl)-1,2,4-triazole (pmta) ligands in a distorted trans-CdCl(2)N(4) octa­hedral...

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Detalles Bibliográficos
Autores principales: Wang, Jian, Li, Zhu-Lai, Xu, Xiu-Zhi, Yan, Wen-Jin, Chi, Hui-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983120/
https://www.ncbi.nlm.nih.gov/pubmed/21587405
http://dx.doi.org/10.1107/S1600536810036251
Descripción
Sumario:In the title coordination polymer, [CdCl(2)(C(8)H(8)N(4))(2)](n), the Cd(II) atom, lying on an inversion center, is coordinated by two Cl atoms and two triazole N atoms and two pyridyl N atoms from four 1-(4-pyridyl­meth­yl)-1,2,4-triazole (pmta) ligands in a distorted trans-CdCl(2)N(4) octa­hedral arrangement. The bridg­ing pmta ligands, with a dihedral angle between the triazole and pyridyl rings of 71.86 (8)°, link the Cd atoms into a 4(4) sheet parallel to ([Image: see text]02). π–π inter­actions between the triazole rings [centroid–centroid distance = 3.428 (2) Å] connect the sheets.