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Poly[dichloridobis[μ-1-(4-pyridylmethyl)-1,2,4-triazole]cadmium(II)]
In the title coordination polymer, [CdCl(2)(C(8)H(8)N(4))(2)](n), the Cd(II) atom, lying on an inversion center, is coordinated by two Cl atoms and two triazole N atoms and two pyridyl N atoms from four 1-(4-pyridylmethyl)-1,2,4-triazole (pmta) ligands in a distorted trans-CdCl(2)N(4) octahedral...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983120/ https://www.ncbi.nlm.nih.gov/pubmed/21587405 http://dx.doi.org/10.1107/S1600536810036251 |
Sumario: | In the title coordination polymer, [CdCl(2)(C(8)H(8)N(4))(2)](n), the Cd(II) atom, lying on an inversion center, is coordinated by two Cl atoms and two triazole N atoms and two pyridyl N atoms from four 1-(4-pyridylmethyl)-1,2,4-triazole (pmta) ligands in a distorted trans-CdCl(2)N(4) octahedral arrangement. The bridging pmta ligands, with a dihedral angle between the triazole and pyridyl rings of 71.86 (8)°, link the Cd atoms into a 4(4) sheet parallel to ([Image: see text]02). π–π interactions between the triazole rings [centroid–centroid distance = 3.428 (2) Å] connect the sheets. |
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