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Poly[dichloridobis[μ-1-(4-pyridyl­meth­yl)-1,2,4-triazole]cadmium(II)]

In the title coordination polymer, [CdCl(2)(C(8)H(8)N(4))(2)](n), the Cd(II) atom, lying on an inversion center, is coordinated by two Cl atoms and two triazole N atoms and two pyridyl N atoms from four 1-(4-pyridyl­meth­yl)-1,2,4-triazole (pmta) ligands in a distorted trans-CdCl(2)N(4) octa­hedral...

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Detalles Bibliográficos
Autores principales: Wang, Jian, Li, Zhu-Lai, Xu, Xiu-Zhi, Yan, Wen-Jin, Chi, Hui-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983120/
https://www.ncbi.nlm.nih.gov/pubmed/21587405
http://dx.doi.org/10.1107/S1600536810036251
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author Wang, Jian
Li, Zhu-Lai
Xu, Xiu-Zhi
Yan, Wen-Jin
Chi, Hui-Li
author_facet Wang, Jian
Li, Zhu-Lai
Xu, Xiu-Zhi
Yan, Wen-Jin
Chi, Hui-Li
author_sort Wang, Jian
collection PubMed
description In the title coordination polymer, [CdCl(2)(C(8)H(8)N(4))(2)](n), the Cd(II) atom, lying on an inversion center, is coordinated by two Cl atoms and two triazole N atoms and two pyridyl N atoms from four 1-(4-pyridyl­meth­yl)-1,2,4-triazole (pmta) ligands in a distorted trans-CdCl(2)N(4) octa­hedral arrangement. The bridg­ing pmta ligands, with a dihedral angle between the triazole and pyridyl rings of 71.86 (8)°, link the Cd atoms into a 4(4) sheet parallel to ([Image: see text]02). π–π inter­actions between the triazole rings [centroid–centroid distance = 3.428 (2) Å] connect the sheets.
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spelling pubmed-29831202010-12-30 Poly[dichloridobis[μ-1-(4-pyridyl­meth­yl)-1,2,4-triazole]cadmium(II)] Wang, Jian Li, Zhu-Lai Xu, Xiu-Zhi Yan, Wen-Jin Chi, Hui-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [CdCl(2)(C(8)H(8)N(4))(2)](n), the Cd(II) atom, lying on an inversion center, is coordinated by two Cl atoms and two triazole N atoms and two pyridyl N atoms from four 1-(4-pyridyl­meth­yl)-1,2,4-triazole (pmta) ligands in a distorted trans-CdCl(2)N(4) octa­hedral arrangement. The bridg­ing pmta ligands, with a dihedral angle between the triazole and pyridyl rings of 71.86 (8)°, link the Cd atoms into a 4(4) sheet parallel to ([Image: see text]02). π–π inter­actions between the triazole rings [centroid–centroid distance = 3.428 (2) Å] connect the sheets. International Union of Crystallography 2010-09-15 /pmc/articles/PMC2983120/ /pubmed/21587405 http://dx.doi.org/10.1107/S1600536810036251 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Jian
Li, Zhu-Lai
Xu, Xiu-Zhi
Yan, Wen-Jin
Chi, Hui-Li
Poly[dichloridobis[μ-1-(4-pyridyl­meth­yl)-1,2,4-triazole]cadmium(II)]
title Poly[dichloridobis[μ-1-(4-pyridyl­meth­yl)-1,2,4-triazole]cadmium(II)]
title_full Poly[dichloridobis[μ-1-(4-pyridyl­meth­yl)-1,2,4-triazole]cadmium(II)]
title_fullStr Poly[dichloridobis[μ-1-(4-pyridyl­meth­yl)-1,2,4-triazole]cadmium(II)]
title_full_unstemmed Poly[dichloridobis[μ-1-(4-pyridyl­meth­yl)-1,2,4-triazole]cadmium(II)]
title_short Poly[dichloridobis[μ-1-(4-pyridyl­meth­yl)-1,2,4-triazole]cadmium(II)]
title_sort poly[dichloridobis[μ-1-(4-pyridyl­meth­yl)-1,2,4-triazole]cadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983120/
https://www.ncbi.nlm.nih.gov/pubmed/21587405
http://dx.doi.org/10.1107/S1600536810036251
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