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Poly[dichloridobis[μ-1-(4-pyridylmethyl)-1,2,4-triazole]cadmium(II)]
In the title coordination polymer, [CdCl(2)(C(8)H(8)N(4))(2)](n), the Cd(II) atom, lying on an inversion center, is coordinated by two Cl atoms and two triazole N atoms and two pyridyl N atoms from four 1-(4-pyridylmethyl)-1,2,4-triazole (pmta) ligands in a distorted trans-CdCl(2)N(4) octahedral...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983120/ https://www.ncbi.nlm.nih.gov/pubmed/21587405 http://dx.doi.org/10.1107/S1600536810036251 |
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author | Wang, Jian Li, Zhu-Lai Xu, Xiu-Zhi Yan, Wen-Jin Chi, Hui-Li |
author_facet | Wang, Jian Li, Zhu-Lai Xu, Xiu-Zhi Yan, Wen-Jin Chi, Hui-Li |
author_sort | Wang, Jian |
collection | PubMed |
description | In the title coordination polymer, [CdCl(2)(C(8)H(8)N(4))(2)](n), the Cd(II) atom, lying on an inversion center, is coordinated by two Cl atoms and two triazole N atoms and two pyridyl N atoms from four 1-(4-pyridylmethyl)-1,2,4-triazole (pmta) ligands in a distorted trans-CdCl(2)N(4) octahedral arrangement. The bridging pmta ligands, with a dihedral angle between the triazole and pyridyl rings of 71.86 (8)°, link the Cd atoms into a 4(4) sheet parallel to ([Image: see text]02). π–π interactions between the triazole rings [centroid–centroid distance = 3.428 (2) Å] connect the sheets. |
format | Text |
id | pubmed-2983120 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29831202010-12-30 Poly[dichloridobis[μ-1-(4-pyridylmethyl)-1,2,4-triazole]cadmium(II)] Wang, Jian Li, Zhu-Lai Xu, Xiu-Zhi Yan, Wen-Jin Chi, Hui-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [CdCl(2)(C(8)H(8)N(4))(2)](n), the Cd(II) atom, lying on an inversion center, is coordinated by two Cl atoms and two triazole N atoms and two pyridyl N atoms from four 1-(4-pyridylmethyl)-1,2,4-triazole (pmta) ligands in a distorted trans-CdCl(2)N(4) octahedral arrangement. The bridging pmta ligands, with a dihedral angle between the triazole and pyridyl rings of 71.86 (8)°, link the Cd atoms into a 4(4) sheet parallel to ([Image: see text]02). π–π interactions between the triazole rings [centroid–centroid distance = 3.428 (2) Å] connect the sheets. International Union of Crystallography 2010-09-15 /pmc/articles/PMC2983120/ /pubmed/21587405 http://dx.doi.org/10.1107/S1600536810036251 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Jian Li, Zhu-Lai Xu, Xiu-Zhi Yan, Wen-Jin Chi, Hui-Li Poly[dichloridobis[μ-1-(4-pyridylmethyl)-1,2,4-triazole]cadmium(II)] |
title | Poly[dichloridobis[μ-1-(4-pyridylmethyl)-1,2,4-triazole]cadmium(II)] |
title_full | Poly[dichloridobis[μ-1-(4-pyridylmethyl)-1,2,4-triazole]cadmium(II)] |
title_fullStr | Poly[dichloridobis[μ-1-(4-pyridylmethyl)-1,2,4-triazole]cadmium(II)] |
title_full_unstemmed | Poly[dichloridobis[μ-1-(4-pyridylmethyl)-1,2,4-triazole]cadmium(II)] |
title_short | Poly[dichloridobis[μ-1-(4-pyridylmethyl)-1,2,4-triazole]cadmium(II)] |
title_sort | poly[dichloridobis[μ-1-(4-pyridylmethyl)-1,2,4-triazole]cadmium(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983120/ https://www.ncbi.nlm.nih.gov/pubmed/21587405 http://dx.doi.org/10.1107/S1600536810036251 |
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