Di-μ-azido-bis­({N′-[1-(2-pyrid­yl-κN)ethyl­idene]acetohydrazidato-κ(2) N′,O}dicopper(II))

The dimeric title compound, [Cu(2)(C(9)H(10)N(3)O)(2)(N(3))(2)], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance...

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Detalles Bibliográficos
Autores principales: Datta, Amitabha, Das, Kuheli, Jhou, Yan-Ming, Huang, Jui-Hsien, Lee, Hon Man
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983124/
https://www.ncbi.nlm.nih.gov/pubmed/21587416
http://dx.doi.org/10.1107/S1600536810034860
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author Datta, Amitabha
Das, Kuheli
Jhou, Yan-Ming
Huang, Jui-Hsien
Lee, Hon Man
author_facet Datta, Amitabha
Das, Kuheli
Jhou, Yan-Ming
Huang, Jui-Hsien
Lee, Hon Man
author_sort Datta, Amitabha
collection PubMed
description The dimeric title compound, [Cu(2)(C(9)H(10)N(3)O)(2)(N(3))(2)], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical inter­molecular C—H⋯N hydrogen bonds link the dimers into chains along the c axis.
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spelling pubmed-29831242010-12-30 Di-μ-azido-bis­({N′-[1-(2-pyrid­yl-κN)ethyl­idene]acetohydrazidato-κ(2) N′,O}dicopper(II)) Datta, Amitabha Das, Kuheli Jhou, Yan-Ming Huang, Jui-Hsien Lee, Hon Man Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dimeric title compound, [Cu(2)(C(9)H(10)N(3)O)(2)(N(3))(2)], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical inter­molecular C—H⋯N hydrogen bonds link the dimers into chains along the c axis. International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983124/ /pubmed/21587416 http://dx.doi.org/10.1107/S1600536810034860 Text en © Datta et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Datta, Amitabha
Das, Kuheli
Jhou, Yan-Ming
Huang, Jui-Hsien
Lee, Hon Man
Di-μ-azido-bis­({N′-[1-(2-pyrid­yl-κN)ethyl­idene]acetohydrazidato-κ(2) N′,O}dicopper(II))
title Di-μ-azido-bis­({N′-[1-(2-pyrid­yl-κN)ethyl­idene]acetohydrazidato-κ(2) N′,O}dicopper(II))
title_full Di-μ-azido-bis­({N′-[1-(2-pyrid­yl-κN)ethyl­idene]acetohydrazidato-κ(2) N′,O}dicopper(II))
title_fullStr Di-μ-azido-bis­({N′-[1-(2-pyrid­yl-κN)ethyl­idene]acetohydrazidato-κ(2) N′,O}dicopper(II))
title_full_unstemmed Di-μ-azido-bis­({N′-[1-(2-pyrid­yl-κN)ethyl­idene]acetohydrazidato-κ(2) N′,O}dicopper(II))
title_short Di-μ-azido-bis­({N′-[1-(2-pyrid­yl-κN)ethyl­idene]acetohydrazidato-κ(2) N′,O}dicopper(II))
title_sort di-μ-azido-bis­({n′-[1-(2-pyrid­yl-κn)ethyl­idene]acetohydrazidato-κ(2) n′,o}dicopper(ii))
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983124/
https://www.ncbi.nlm.nih.gov/pubmed/21587416
http://dx.doi.org/10.1107/S1600536810034860
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AT huangjuihsien dimazidobisn12pyridylknethylideneacetohydrazidatok2nodicopperii
AT leehonman dimazidobisn12pyridylknethylideneacetohydrazidatok2nodicopperii

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