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Octamethylbis(μ(2)-2-methylbenzoato-κ(2) O:O′)bis(2-methylbenzoato-κO)di-μ(3)-oxido-tetratin(IV)
The title compound, [Sn(4)(CH(3))(8)(C(8)H(7)O(2))(4)O(2)], is a distannoxane derivative of 2-methylbenzoic acid. The crystal structure is composed of centrosymmetric dimers lying about inversion centres. Both independent Sn atoms adopt distorted trigonal-bipyramidal SnC(2)O(3) coordination geomet...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983126/ https://www.ncbi.nlm.nih.gov/pubmed/21587414 http://dx.doi.org/10.1107/S1600536810036512 |
Sumario: | The title compound, [Sn(4)(CH(3))(8)(C(8)H(7)O(2))(4)O(2)], is a distannoxane derivative of 2-methylbenzoic acid. The crystal structure is composed of centrosymmetric dimers lying about inversion centres. Both independent Sn atoms adopt distorted trigonal-bipyramidal SnC(2)O(3) coordination geometries with the basal planes consisting of two C-atoms from the methyl groups and a bridging O atom. The Sn—C and Sn—O bond lengths lie in the ranges 2.090 (2)–2.104 (3) and 2.0241 (14)–2.2561 (15) Å, respectively. The central four-membered planar Sn(2)O(2) ring [Sn⋯Sn distance = 3.2993 (2) Å] makes dihedral angles of 5.43 (11) and 59.50 (7)° with the methylphenyl groups, which are themselves oriented at a dihedral angle of 61.38 (8)°. Besides weak C—H⋯O and C—H⋯π interactions, the packing mainly features van der Waals forces between the molecules. |
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