Cargando…
Octamethylbis(μ(2)-2-methylbenzoato-κ(2) O:O′)bis(2-methylbenzoato-κO)di-μ(3)-oxido-tetratin(IV)
The title compound, [Sn(4)(CH(3))(8)(C(8)H(7)O(2))(4)O(2)], is a distannoxane derivative of 2-methylbenzoic acid. The crystal structure is composed of centrosymmetric dimers lying about inversion centres. Both independent Sn atoms adopt distorted trigonal-bipyramidal SnC(2)O(3) coordination geomet...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983126/ https://www.ncbi.nlm.nih.gov/pubmed/21587414 http://dx.doi.org/10.1107/S1600536810036512 |
_version_ | 1782191806653399040 |
---|---|
author | Danish, Muhammad Ghafoor, Sabiha Tahir, M. Nawaz Ahmad, Nazir Hamid, Masood |
author_facet | Danish, Muhammad Ghafoor, Sabiha Tahir, M. Nawaz Ahmad, Nazir Hamid, Masood |
author_sort | Danish, Muhammad |
collection | PubMed |
description | The title compound, [Sn(4)(CH(3))(8)(C(8)H(7)O(2))(4)O(2)], is a distannoxane derivative of 2-methylbenzoic acid. The crystal structure is composed of centrosymmetric dimers lying about inversion centres. Both independent Sn atoms adopt distorted trigonal-bipyramidal SnC(2)O(3) coordination geometries with the basal planes consisting of two C-atoms from the methyl groups and a bridging O atom. The Sn—C and Sn—O bond lengths lie in the ranges 2.090 (2)–2.104 (3) and 2.0241 (14)–2.2561 (15) Å, respectively. The central four-membered planar Sn(2)O(2) ring [Sn⋯Sn distance = 3.2993 (2) Å] makes dihedral angles of 5.43 (11) and 59.50 (7)° with the methylphenyl groups, which are themselves oriented at a dihedral angle of 61.38 (8)°. Besides weak C—H⋯O and C—H⋯π interactions, the packing mainly features van der Waals forces between the molecules. |
format | Text |
id | pubmed-2983126 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29831262010-12-30 Octamethylbis(μ(2)-2-methylbenzoato-κ(2) O:O′)bis(2-methylbenzoato-κO)di-μ(3)-oxido-tetratin(IV) Danish, Muhammad Ghafoor, Sabiha Tahir, M. Nawaz Ahmad, Nazir Hamid, Masood Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(4)(CH(3))(8)(C(8)H(7)O(2))(4)O(2)], is a distannoxane derivative of 2-methylbenzoic acid. The crystal structure is composed of centrosymmetric dimers lying about inversion centres. Both independent Sn atoms adopt distorted trigonal-bipyramidal SnC(2)O(3) coordination geometries with the basal planes consisting of two C-atoms from the methyl groups and a bridging O atom. The Sn—C and Sn—O bond lengths lie in the ranges 2.090 (2)–2.104 (3) and 2.0241 (14)–2.2561 (15) Å, respectively. The central four-membered planar Sn(2)O(2) ring [Sn⋯Sn distance = 3.2993 (2) Å] makes dihedral angles of 5.43 (11) and 59.50 (7)° with the methylphenyl groups, which are themselves oriented at a dihedral angle of 61.38 (8)°. Besides weak C—H⋯O and C—H⋯π interactions, the packing mainly features van der Waals forces between the molecules. International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983126/ /pubmed/21587414 http://dx.doi.org/10.1107/S1600536810036512 Text en © Danish et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Danish, Muhammad Ghafoor, Sabiha Tahir, M. Nawaz Ahmad, Nazir Hamid, Masood Octamethylbis(μ(2)-2-methylbenzoato-κ(2) O:O′)bis(2-methylbenzoato-κO)di-μ(3)-oxido-tetratin(IV) |
title | Octamethylbis(μ(2)-2-methylbenzoato-κ(2)
O:O′)bis(2-methylbenzoato-κO)di-μ(3)-oxido-tetratin(IV) |
title_full | Octamethylbis(μ(2)-2-methylbenzoato-κ(2)
O:O′)bis(2-methylbenzoato-κO)di-μ(3)-oxido-tetratin(IV) |
title_fullStr | Octamethylbis(μ(2)-2-methylbenzoato-κ(2)
O:O′)bis(2-methylbenzoato-κO)di-μ(3)-oxido-tetratin(IV) |
title_full_unstemmed | Octamethylbis(μ(2)-2-methylbenzoato-κ(2)
O:O′)bis(2-methylbenzoato-κO)di-μ(3)-oxido-tetratin(IV) |
title_short | Octamethylbis(μ(2)-2-methylbenzoato-κ(2)
O:O′)bis(2-methylbenzoato-κO)di-μ(3)-oxido-tetratin(IV) |
title_sort | octamethylbis(μ(2)-2-methylbenzoato-κ(2)
o:o′)bis(2-methylbenzoato-κo)di-μ(3)-oxido-tetratin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983126/ https://www.ncbi.nlm.nih.gov/pubmed/21587414 http://dx.doi.org/10.1107/S1600536810036512 |
work_keys_str_mv | AT danishmuhammad octamethylbism22methylbenzoatok2oobis2methylbenzoatokodim3oxidotetratiniv AT ghafoorsabiha octamethylbism22methylbenzoatok2oobis2methylbenzoatokodim3oxidotetratiniv AT tahirmnawaz octamethylbism22methylbenzoatok2oobis2methylbenzoatokodim3oxidotetratiniv AT ahmadnazir octamethylbism22methylbenzoatok2oobis2methylbenzoatokodim3oxidotetratiniv AT hamidmasood octamethylbism22methylbenzoatok2oobis2methylbenzoatokodim3oxidotetratiniv |