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Octa­methyl­bis­(μ(2)-2-methyl­benzoato-κ(2) O:O′)bis­(2-methyl­benzoato-κO)di-μ(3)-oxido-tetra­tin(IV)

The title compound, [Sn(4)(CH(3))(8)(C(8)H(7)O(2))(4)O(2)], is a distann­oxane derivative of 2-methyl­benzoic acid. The crystal structure is composed of centrosymmetric dimers lying about inversion centres. Both independent Sn atoms adopt distorted trigonal-bipyramidal SnC(2)O(3) coordination geomet...

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Autores principales: Danish, Muhammad, Ghafoor, Sabiha, Tahir, M. Nawaz, Ahmad, Nazir, Hamid, Masood
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983126/
https://www.ncbi.nlm.nih.gov/pubmed/21587414
http://dx.doi.org/10.1107/S1600536810036512
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author Danish, Muhammad
Ghafoor, Sabiha
Tahir, M. Nawaz
Ahmad, Nazir
Hamid, Masood
author_facet Danish, Muhammad
Ghafoor, Sabiha
Tahir, M. Nawaz
Ahmad, Nazir
Hamid, Masood
author_sort Danish, Muhammad
collection PubMed
description The title compound, [Sn(4)(CH(3))(8)(C(8)H(7)O(2))(4)O(2)], is a distann­oxane derivative of 2-methyl­benzoic acid. The crystal structure is composed of centrosymmetric dimers lying about inversion centres. Both independent Sn atoms adopt distorted trigonal-bipyramidal SnC(2)O(3) coordination geometries with the basal planes consisting of two C-atoms from the methyl groups and a bridging O atom. The Sn—C and Sn—O bond lengths lie in the ranges 2.090 (2)–2.104 (3) and 2.0241 (14)–2.2561 (15) Å, respectively. The central four-membered planar Sn(2)O(2) ring [Sn⋯Sn distance = 3.2993 (2) Å] makes dihedral angles of 5.43 (11) and 59.50 (7)° with the methyl­phenyl groups, which are themselves oriented at a dihedral angle of 61.38 (8)°. Besides weak C—H⋯O and C—H⋯π inter­actions, the packing mainly features van der Waals forces between the mol­ecules.
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spelling pubmed-29831262010-12-30 Octa­methyl­bis­(μ(2)-2-methyl­benzoato-κ(2) O:O′)bis­(2-methyl­benzoato-κO)di-μ(3)-oxido-tetra­tin(IV) Danish, Muhammad Ghafoor, Sabiha Tahir, M. Nawaz Ahmad, Nazir Hamid, Masood Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(4)(CH(3))(8)(C(8)H(7)O(2))(4)O(2)], is a distann­oxane derivative of 2-methyl­benzoic acid. The crystal structure is composed of centrosymmetric dimers lying about inversion centres. Both independent Sn atoms adopt distorted trigonal-bipyramidal SnC(2)O(3) coordination geometries with the basal planes consisting of two C-atoms from the methyl groups and a bridging O atom. The Sn—C and Sn—O bond lengths lie in the ranges 2.090 (2)–2.104 (3) and 2.0241 (14)–2.2561 (15) Å, respectively. The central four-membered planar Sn(2)O(2) ring [Sn⋯Sn distance = 3.2993 (2) Å] makes dihedral angles of 5.43 (11) and 59.50 (7)° with the methyl­phenyl groups, which are themselves oriented at a dihedral angle of 61.38 (8)°. Besides weak C—H⋯O and C—H⋯π inter­actions, the packing mainly features van der Waals forces between the mol­ecules. International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983126/ /pubmed/21587414 http://dx.doi.org/10.1107/S1600536810036512 Text en © Danish et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Danish, Muhammad
Ghafoor, Sabiha
Tahir, M. Nawaz
Ahmad, Nazir
Hamid, Masood
Octa­methyl­bis­(μ(2)-2-methyl­benzoato-κ(2) O:O′)bis­(2-methyl­benzoato-κO)di-μ(3)-oxido-tetra­tin(IV)
title Octa­methyl­bis­(μ(2)-2-methyl­benzoato-κ(2) O:O′)bis­(2-methyl­benzoato-κO)di-μ(3)-oxido-tetra­tin(IV)
title_full Octa­methyl­bis­(μ(2)-2-methyl­benzoato-κ(2) O:O′)bis­(2-methyl­benzoato-κO)di-μ(3)-oxido-tetra­tin(IV)
title_fullStr Octa­methyl­bis­(μ(2)-2-methyl­benzoato-κ(2) O:O′)bis­(2-methyl­benzoato-κO)di-μ(3)-oxido-tetra­tin(IV)
title_full_unstemmed Octa­methyl­bis­(μ(2)-2-methyl­benzoato-κ(2) O:O′)bis­(2-methyl­benzoato-κO)di-μ(3)-oxido-tetra­tin(IV)
title_short Octa­methyl­bis­(μ(2)-2-methyl­benzoato-κ(2) O:O′)bis­(2-methyl­benzoato-κO)di-μ(3)-oxido-tetra­tin(IV)
title_sort octa­methyl­bis­(μ(2)-2-methyl­benzoato-κ(2) o:o′)bis­(2-methyl­benzoato-κo)di-μ(3)-oxido-tetra­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983126/
https://www.ncbi.nlm.nih.gov/pubmed/21587414
http://dx.doi.org/10.1107/S1600536810036512
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