1-[(4-Chloro­phen­yl)(phenyl­imino)­meth­yl]-7-meth­oxy-2-naphthol–1,4-diaza­bicyclo­[2.2.2]octane (2/1)

In the crystal structure of the title cocrystal, 2C(24)H(18)ClNO(2)·C(6)H(12)N(2), the 1,4-diaza­bicyclo­[2.2.2]octane mol­ecule is located on a twofold rotation axis and linked to the two triaryl­imine mol­ecules by O—H⋯N hydrogen bonds, forming a 2:1 aggregate. C—H⋯Cl inter­actions are also observ...

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Autores principales: Nagasawa, Atsushi, Mitsui, Ryosuke, Kato, Yuichi, Okamoto, Akiko, Yonezawa, Noriyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983128/
https://www.ncbi.nlm.nih.gov/pubmed/21587495
http://dx.doi.org/10.1107/S1600536810034690
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author Nagasawa, Atsushi
Mitsui, Ryosuke
Kato, Yuichi
Okamoto, Akiko
Yonezawa, Noriyuki
author_facet Nagasawa, Atsushi
Mitsui, Ryosuke
Kato, Yuichi
Okamoto, Akiko
Yonezawa, Noriyuki
author_sort Nagasawa, Atsushi
collection PubMed
description In the crystal structure of the title cocrystal, 2C(24)H(18)ClNO(2)·C(6)H(12)N(2), the 1,4-diaza­bicyclo­[2.2.2]octane mol­ecule is located on a twofold rotation axis and linked to the two triaryl­imine mol­ecules by O—H⋯N hydrogen bonds, forming a 2:1 aggregate. C—H⋯Cl inter­actions are also observed. In the triaryl­imine mol­ecule, the naphthalene ring system makes dihedral angles of 80.39 (6) and 82.35 (6)°, respectively, with the phenyl and benzene rings. The dihedral angle between these two latter rings is 87.09 (7)°.
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spelling pubmed-29831282010-12-30 1-[(4-Chloro­phen­yl)(phenyl­imino)­meth­yl]-7-meth­oxy-2-naphthol–1,4-diaza­bicyclo­[2.2.2]octane (2/1) Nagasawa, Atsushi Mitsui, Ryosuke Kato, Yuichi Okamoto, Akiko Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title cocrystal, 2C(24)H(18)ClNO(2)·C(6)H(12)N(2), the 1,4-diaza­bicyclo­[2.2.2]octane mol­ecule is located on a twofold rotation axis and linked to the two triaryl­imine mol­ecules by O—H⋯N hydrogen bonds, forming a 2:1 aggregate. C—H⋯Cl inter­actions are also observed. In the triaryl­imine mol­ecule, the naphthalene ring system makes dihedral angles of 80.39 (6) and 82.35 (6)°, respectively, with the phenyl and benzene rings. The dihedral angle between these two latter rings is 87.09 (7)°. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983128/ /pubmed/21587495 http://dx.doi.org/10.1107/S1600536810034690 Text en © Nagasawa et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nagasawa, Atsushi
Mitsui, Ryosuke
Kato, Yuichi
Okamoto, Akiko
Yonezawa, Noriyuki
1-[(4-Chloro­phen­yl)(phenyl­imino)­meth­yl]-7-meth­oxy-2-naphthol–1,4-diaza­bicyclo­[2.2.2]octane (2/1)
title 1-[(4-Chloro­phen­yl)(phenyl­imino)­meth­yl]-7-meth­oxy-2-naphthol–1,4-diaza­bicyclo­[2.2.2]octane (2/1)
title_full 1-[(4-Chloro­phen­yl)(phenyl­imino)­meth­yl]-7-meth­oxy-2-naphthol–1,4-diaza­bicyclo­[2.2.2]octane (2/1)
title_fullStr 1-[(4-Chloro­phen­yl)(phenyl­imino)­meth­yl]-7-meth­oxy-2-naphthol–1,4-diaza­bicyclo­[2.2.2]octane (2/1)
title_full_unstemmed 1-[(4-Chloro­phen­yl)(phenyl­imino)­meth­yl]-7-meth­oxy-2-naphthol–1,4-diaza­bicyclo­[2.2.2]octane (2/1)
title_short 1-[(4-Chloro­phen­yl)(phenyl­imino)­meth­yl]-7-meth­oxy-2-naphthol–1,4-diaza­bicyclo­[2.2.2]octane (2/1)
title_sort 1-[(4-chloro­phen­yl)(phenyl­imino)­meth­yl]-7-meth­oxy-2-naphthol–1,4-diaza­bicyclo­[2.2.2]octane (2/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983128/
https://www.ncbi.nlm.nih.gov/pubmed/21587495
http://dx.doi.org/10.1107/S1600536810034690
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AT katoyuichi 14chlorophenylphenyliminomethyl7methoxy2naphthol14diazabicyclo222octane21
AT okamotoakiko 14chlorophenylphenyliminomethyl7methoxy2naphthol14diazabicyclo222octane21
AT yonezawanoriyuki 14chlorophenylphenyliminomethyl7methoxy2naphthol14diazabicyclo222octane21

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