Bis(carbonyl-κC)(N,N-dimethyl­thio­carbamoyl-κ(2) C,S)(pyridine-2-thiol­ato-κ(2) N,S)(triphenyl­phosphine-κP)molybdenum(II)

There are two independent mol­ecules with similar configurations in the title complex, [Mo(C(3)H(6)NS)(C(5)H(4)NS)(C(18)H(15)P)(CO)(2)]. The geometry around the metal atom is that of a capped octa­hedron. The thio­cabamoyl and pyridine-2-thiol­ate ligands coordinate to the molybdenum metal center th...

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Detalles Bibliográficos
Autores principales: Yih, Kuang-Hway, Wang, Hsiao-Fen, Lee, Gene-Hsiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983129/
https://www.ncbi.nlm.nih.gov/pubmed/21587354
http://dx.doi.org/10.1107/S1600536810034562
Descripción
Sumario:There are two independent mol­ecules with similar configurations in the title complex, [Mo(C(3)H(6)NS)(C(5)H(4)NS)(C(18)H(15)P)(CO)(2)]. The geometry around the metal atom is that of a capped octa­hedron. The thio­cabamoyl and pyridine-2-thiol­ate ligands coordinate to the molybdenum metal center through the C and S atoms, and N and S atoms, respectively. NMR, IR and MS analyses are in agreement with the structure of the title compound.

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