Bis(carbonyl-κC)(N,N-dimethyl­thio­carbamoyl-κ(2) C,S)(pyridine-2-thiol­ato-κ(2) N,S)(triphenyl­phosphine-κP)molybdenum(II)

There are two independent mol­ecules with similar configurations in the title complex, [Mo(C(3)H(6)NS)(C(5)H(4)NS)(C(18)H(15)P)(CO)(2)]. The geometry around the metal atom is that of a capped octa­hedron. The thio­cabamoyl and pyridine-2-thiol­ate ligands coordinate to the molybdenum metal center th...

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Detalles Bibliográficos
Autores principales: Yih, Kuang-Hway, Wang, Hsiao-Fen, Lee, Gene-Hsiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983129/
https://www.ncbi.nlm.nih.gov/pubmed/21587354
http://dx.doi.org/10.1107/S1600536810034562
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author Yih, Kuang-Hway
Wang, Hsiao-Fen
Lee, Gene-Hsiang
author_facet Yih, Kuang-Hway
Wang, Hsiao-Fen
Lee, Gene-Hsiang
author_sort Yih, Kuang-Hway
collection PubMed
description There are two independent mol­ecules with similar configurations in the title complex, [Mo(C(3)H(6)NS)(C(5)H(4)NS)(C(18)H(15)P)(CO)(2)]. The geometry around the metal atom is that of a capped octa­hedron. The thio­cabamoyl and pyridine-2-thiol­ate ligands coordinate to the molybdenum metal center through the C and S atoms, and N and S atoms, respectively. NMR, IR and MS analyses are in agreement with the structure of the title compound.
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spelling pubmed-29831292010-12-30 Bis(carbonyl-κC)(N,N-dimethyl­thio­carbamoyl-κ(2) C,S)(pyridine-2-thiol­ato-κ(2) N,S)(triphenyl­phosphine-κP)molybdenum(II) Yih, Kuang-Hway Wang, Hsiao-Fen Lee, Gene-Hsiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers There are two independent mol­ecules with similar configurations in the title complex, [Mo(C(3)H(6)NS)(C(5)H(4)NS)(C(18)H(15)P)(CO)(2)]. The geometry around the metal atom is that of a capped octa­hedron. The thio­cabamoyl and pyridine-2-thiol­ate ligands coordinate to the molybdenum metal center through the C and S atoms, and N and S atoms, respectively. NMR, IR and MS analyses are in agreement with the structure of the title compound. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983129/ /pubmed/21587354 http://dx.doi.org/10.1107/S1600536810034562 Text en © Yih et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yih, Kuang-Hway
Wang, Hsiao-Fen
Lee, Gene-Hsiang
Bis(carbonyl-κC)(N,N-dimethyl­thio­carbamoyl-κ(2) C,S)(pyridine-2-thiol­ato-κ(2) N,S)(triphenyl­phosphine-κP)molybdenum(II)
title Bis(carbonyl-κC)(N,N-dimethyl­thio­carbamoyl-κ(2) C,S)(pyridine-2-thiol­ato-κ(2) N,S)(triphenyl­phosphine-κP)molybdenum(II)
title_full Bis(carbonyl-κC)(N,N-dimethyl­thio­carbamoyl-κ(2) C,S)(pyridine-2-thiol­ato-κ(2) N,S)(triphenyl­phosphine-κP)molybdenum(II)
title_fullStr Bis(carbonyl-κC)(N,N-dimethyl­thio­carbamoyl-κ(2) C,S)(pyridine-2-thiol­ato-κ(2) N,S)(triphenyl­phosphine-κP)molybdenum(II)
title_full_unstemmed Bis(carbonyl-κC)(N,N-dimethyl­thio­carbamoyl-κ(2) C,S)(pyridine-2-thiol­ato-κ(2) N,S)(triphenyl­phosphine-κP)molybdenum(II)
title_short Bis(carbonyl-κC)(N,N-dimethyl­thio­carbamoyl-κ(2) C,S)(pyridine-2-thiol­ato-κ(2) N,S)(triphenyl­phosphine-κP)molybdenum(II)
title_sort bis(carbonyl-κc)(n,n-dimethyl­thio­carbamoyl-κ(2) c,s)(pyridine-2-thiol­ato-κ(2) n,s)(triphenyl­phosphine-κp)molybdenum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983129/
https://www.ncbi.nlm.nih.gov/pubmed/21587354
http://dx.doi.org/10.1107/S1600536810034562
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AT wanghsiaofen biscarbonylkcnndimethylthiocarbamoylk2cspyridine2thiolatok2nstriphenylphosphinekpmolybdenumii
AT leegenehsiang biscarbonylkcnndimethylthiocarbamoylk2cspyridine2thiolatok2nstriphenylphosphinekpmolybdenumii

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