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(Dimethylformamide-κO)(2-hydroxybenzoato-κ(2) O (1),O (1′))[tris(1-methyl-1H-benzimidazol-2-ylmethyl-κN (3))amine-κN]manganese(II) perchlorate dimethylformamide monosolvate
In the title complex, [Mn(C(7)H(5)O(3))(C(27)H(27)N(7))(C(3)H(7)NO)]ClO(4)·C(3)H(7)NO, the Mn(II) ion is coordinated in a slightly distorted monocapped trigonal-prismatic geometry. The tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine (Mentb) ligand coordinates in a tetradentate mode and the coordin...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983134/ https://www.ncbi.nlm.nih.gov/pubmed/21587401 http://dx.doi.org/10.1107/S160053681003610X |
| _version_ | 1782191808589070336 |
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| author | Wu, Huilu Bai, Ying Huang, Xingcai Meng, Xuan Qi, Baoliang |
| author_facet | Wu, Huilu Bai, Ying Huang, Xingcai Meng, Xuan Qi, Baoliang |
| author_sort | Wu, Huilu |
| collection | PubMed |
| description | In the title complex, [Mn(C(7)H(5)O(3))(C(27)H(27)N(7))(C(3)H(7)NO)]ClO(4)·C(3)H(7)NO, the Mn(II) ion is coordinated in a slightly distorted monocapped trigonal-prismatic geometry. The tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine (Mentb) ligand coordinates in a tetradentate mode and the coordination is completed by a bis-chelating salicylate ligand and a dimethylformamide ligand. The hydroxy group and the ortho H atoms of the salicylate ligand were refined as disordered over two sites with occupancies of 0.581 (8) and 0.419 (8). Both disorder components of the hydroxy group form intramolecular O—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-2983134 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29831342010-12-30 (Dimethylformamide-κO)(2-hydroxybenzoato-κ(2) O (1),O (1′))[tris(1-methyl-1H-benzimidazol-2-ylmethyl-κN (3))amine-κN]manganese(II) perchlorate dimethylformamide monosolvate Wu, Huilu Bai, Ying Huang, Xingcai Meng, Xuan Qi, Baoliang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(7)H(5)O(3))(C(27)H(27)N(7))(C(3)H(7)NO)]ClO(4)·C(3)H(7)NO, the Mn(II) ion is coordinated in a slightly distorted monocapped trigonal-prismatic geometry. The tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine (Mentb) ligand coordinates in a tetradentate mode and the coordination is completed by a bis-chelating salicylate ligand and a dimethylformamide ligand. The hydroxy group and the ortho H atoms of the salicylate ligand were refined as disordered over two sites with occupancies of 0.581 (8) and 0.419 (8). Both disorder components of the hydroxy group form intramolecular O—H⋯O hydrogen bonds. International Union of Crystallography 2010-09-11 /pmc/articles/PMC2983134/ /pubmed/21587401 http://dx.doi.org/10.1107/S160053681003610X Text en © Wu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wu, Huilu Bai, Ying Huang, Xingcai Meng, Xuan Qi, Baoliang (Dimethylformamide-κO)(2-hydroxybenzoato-κ(2) O (1),O (1′))[tris(1-methyl-1H-benzimidazol-2-ylmethyl-κN (3))amine-κN]manganese(II) perchlorate dimethylformamide monosolvate |
| title | (Dimethylformamide-κO)(2-hydroxybenzoato-κ(2)
O
(1),O
(1′))[tris(1-methyl-1H-benzimidazol-2-ylmethyl-κN
(3))amine-κN]manganese(II) perchlorate dimethylformamide monosolvate |
| title_full | (Dimethylformamide-κO)(2-hydroxybenzoato-κ(2)
O
(1),O
(1′))[tris(1-methyl-1H-benzimidazol-2-ylmethyl-κN
(3))amine-κN]manganese(II) perchlorate dimethylformamide monosolvate |
| title_fullStr | (Dimethylformamide-κO)(2-hydroxybenzoato-κ(2)
O
(1),O
(1′))[tris(1-methyl-1H-benzimidazol-2-ylmethyl-κN
(3))amine-κN]manganese(II) perchlorate dimethylformamide monosolvate |
| title_full_unstemmed | (Dimethylformamide-κO)(2-hydroxybenzoato-κ(2)
O
(1),O
(1′))[tris(1-methyl-1H-benzimidazol-2-ylmethyl-κN
(3))amine-κN]manganese(II) perchlorate dimethylformamide monosolvate |
| title_short | (Dimethylformamide-κO)(2-hydroxybenzoato-κ(2)
O
(1),O
(1′))[tris(1-methyl-1H-benzimidazol-2-ylmethyl-κN
(3))amine-κN]manganese(II) perchlorate dimethylformamide monosolvate |
| title_sort | (dimethylformamide-κo)(2-hydroxybenzoato-κ(2)
o
(1),o
(1′))[tris(1-methyl-1h-benzimidazol-2-ylmethyl-κn
(3))amine-κn]manganese(ii) perchlorate dimethylformamide monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983134/ https://www.ncbi.nlm.nih.gov/pubmed/21587401 http://dx.doi.org/10.1107/S160053681003610X |
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