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[μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)butane-1,4-diamine]bis[diacetatocadmium(II)] nonahydrate
The title dinuclear complex, [Cd(2)(CH(3)CO(2))(4)(C(28)H(32)N(6))]·9H(2)O, is located on a crystallographic inversion center. The unique Cd(II) ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolylamine unit of the ligand via the N atoms in a meridiona...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983136/ https://www.ncbi.nlm.nih.gov/pubmed/21587357 http://dx.doi.org/10.1107/S1600536810034550 |
Sumario: | The title dinuclear complex, [Cd(2)(CH(3)CO(2))(4)(C(28)H(32)N(6))]·9H(2)O, is located on a crystallographic inversion center. The unique Cd(II) ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolylamine unit of the ligand via the N atoms in a meridional fashion and two O atoms of the acetate ligands with short Cd—O distances. The coordination is completed by two loosely bound O atoms of the acetate ligands. The Cd—N distances involving the pyridine N atoms differ slightly from each other and the Cd—N distance involving the tertiary N atom is the longest. In the crystal structure, complex molecules and solvent water molecules are connected into a three-dimensional network via intermolecular O—H⋯O hydrogen bonds. One of the water molecules lies on a twofold rotation axis. |
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