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[μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[diacetato­cadmium(II)] nona­hydrate

The title dinuclear complex, [Cd(2)(CH(3)CO(2))(4)(C(28)H(32)N(6))]·9H(2)O, is located on a crystallographic inversion center. The unique Cd(II) ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolyl­amine unit of the ligand via the N atoms in a meridiona...

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Detalles Bibliográficos
Autores principales: Bartholomä, Mark, Cheung, Hoi, Zubieta, Jon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983136/
https://www.ncbi.nlm.nih.gov/pubmed/21587357
http://dx.doi.org/10.1107/S1600536810034550
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author Bartholomä, Mark
Cheung, Hoi
Zubieta, Jon
author_facet Bartholomä, Mark
Cheung, Hoi
Zubieta, Jon
author_sort Bartholomä, Mark
collection PubMed
description The title dinuclear complex, [Cd(2)(CH(3)CO(2))(4)(C(28)H(32)N(6))]·9H(2)O, is located on a crystallographic inversion center. The unique Cd(II) ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolyl­amine unit of the ligand via the N atoms in a meridional fashion and two O atoms of the acetate ligands with short Cd—O distances. The coordination is completed by two loosely bound O atoms of the acetate ligands. The Cd—N distances involving the pyridine N atoms differ slightly from each other and the Cd—N distance involving the tertiary N atom is the longest. In the crystal structure, complex mol­ecules and solvent water mol­ecules are connected into a three-dimensional network via inter­molecular O—H⋯O hydrogen bonds. One of the water mol­ecules lies on a twofold rotation axis.
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spelling pubmed-29831362010-12-30 [μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[diacetato­cadmium(II)] nona­hydrate Bartholomä, Mark Cheung, Hoi Zubieta, Jon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title dinuclear complex, [Cd(2)(CH(3)CO(2))(4)(C(28)H(32)N(6))]·9H(2)O, is located on a crystallographic inversion center. The unique Cd(II) ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolyl­amine unit of the ligand via the N atoms in a meridional fashion and two O atoms of the acetate ligands with short Cd—O distances. The coordination is completed by two loosely bound O atoms of the acetate ligands. The Cd—N distances involving the pyridine N atoms differ slightly from each other and the Cd—N distance involving the tertiary N atom is the longest. In the crystal structure, complex mol­ecules and solvent water mol­ecules are connected into a three-dimensional network via inter­molecular O—H⋯O hydrogen bonds. One of the water mol­ecules lies on a twofold rotation axis. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983136/ /pubmed/21587357 http://dx.doi.org/10.1107/S1600536810034550 Text en © Bartholomä et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bartholomä, Mark
Cheung, Hoi
Zubieta, Jon
[μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[diacetato­cadmium(II)] nona­hydrate
title [μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[diacetato­cadmium(II)] nona­hydrate
title_full [μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[diacetato­cadmium(II)] nona­hydrate
title_fullStr [μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[diacetato­cadmium(II)] nona­hydrate
title_full_unstemmed [μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[diacetato­cadmium(II)] nona­hydrate
title_short [μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[diacetato­cadmium(II)] nona­hydrate
title_sort [μ-n,n,n′,n′-tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[diacetato­cadmium(ii)] nona­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983136/
https://www.ncbi.nlm.nih.gov/pubmed/21587357
http://dx.doi.org/10.1107/S1600536810034550
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