{Bis[2-(3,5-dimethyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate

The title compound, [PdCl(C(14)H(23)N(5))]Cl·0.25H(2)O, is a pseudopolymorph of the previously reported compound [PdCl(C(14)H(23)N(5))]Cl·2H(2)O [de Mendoza et al. (2006 ▶). Acta Cryst. E62, m2934–m2936]. The cationic complex and chloride anion are disordered over two positions each in a 0.584 (4):0...

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Detalles Bibliográficos
Autores principales: Guzei, Ilia A., Spencer, Lara C., Miti, Nangamso, Darkwa, James
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983137/
https://www.ncbi.nlm.nih.gov/pubmed/21587393
http://dx.doi.org/10.1107/S1600536810035427
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author Guzei, Ilia A.
Spencer, Lara C.
Miti, Nangamso
Darkwa, James
author_facet Guzei, Ilia A.
Spencer, Lara C.
Miti, Nangamso
Darkwa, James
author_sort Guzei, Ilia A.
collection PubMed
description The title compound, [PdCl(C(14)H(23)N(5))]Cl·0.25H(2)O, is a pseudopolymorph of the previously reported compound [PdCl(C(14)H(23)N(5))]Cl·2H(2)O [de Mendoza et al. (2006 ▶). Acta Cryst. E62, m2934–m2936]. The cationic complex and chloride anion are disordered over two positions each in a 0.584 (4):0.416 (4) ratio. The geometry about the Pd atom is distorted square-planar. The pyrazole rings are almost perpendicular, forming a dihedral angle of 86.6 (6)° to each other, to mitigate steric conflict between their methyl groups.
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spelling pubmed-29831372010-12-30 {Bis[2-(3,5-dimethyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate Guzei, Ilia A. Spencer, Lara C. Miti, Nangamso Darkwa, James Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PdCl(C(14)H(23)N(5))]Cl·0.25H(2)O, is a pseudopolymorph of the previously reported compound [PdCl(C(14)H(23)N(5))]Cl·2H(2)O [de Mendoza et al. (2006 ▶). Acta Cryst. E62, m2934–m2936]. The cationic complex and chloride anion are disordered over two positions each in a 0.584 (4):0.416 (4) ratio. The geometry about the Pd atom is distorted square-planar. The pyrazole rings are almost perpendicular, forming a dihedral angle of 86.6 (6)° to each other, to mitigate steric conflict between their methyl groups. International Union of Crystallography 2010-09-11 /pmc/articles/PMC2983137/ /pubmed/21587393 http://dx.doi.org/10.1107/S1600536810035427 Text en © Guzei et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guzei, Ilia A.
Spencer, Lara C.
Miti, Nangamso
Darkwa, James
{Bis[2-(3,5-dimethyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate
title {Bis[2-(3,5-dimethyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate
title_full {Bis[2-(3,5-dimethyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate
title_fullStr {Bis[2-(3,5-dimethyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate
title_full_unstemmed {Bis[2-(3,5-dimethyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate
title_short {Bis[2-(3,5-dimethyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate
title_sort {bis[2-(3,5-dimethyl­pyrazol-1-yl-κn (2))eth­yl]amine-κn}chloridopalladium(ii) chloride 0.25-hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983137/
https://www.ncbi.nlm.nih.gov/pubmed/21587393
http://dx.doi.org/10.1107/S1600536810035427
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AT spencerlarac bis235dimethylpyrazol1ylkn2ethylamineknchloridopalladiumiichloride025hydrate
AT mitinangamso bis235dimethylpyrazol1ylkn2ethylamineknchloridopalladiumiichloride025hydrate
AT darkwajames bis235dimethylpyrazol1ylkn2ethylamineknchloridopalladiumiichloride025hydrate

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