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Aqua­(trifluoro­methane­sulfonato)­bis­(1,3,7-trimethyl­purine-2,6-dione)silver(I)

In the title compound, [Ag(CF(3)SO(3))(C(8)H(10)N(4)O(2))(2)(H(2)O)], the Ag(I) atom is coordinated by two caffeine N atoms and, at longer distances, two O atoms of a coordinated water mol­ecule and the trifluoro­methane­sulfonate anion, resulting in an AgN(2)O(2) seesaw geometry. The caffeine mol­e...

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Detalles Bibliográficos
Autores principales: Arman, Hadi D., Miller, Tyler, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983140/
https://www.ncbi.nlm.nih.gov/pubmed/21587369
http://dx.doi.org/10.1107/S1600536810035300
Descripción
Sumario:In the title compound, [Ag(CF(3)SO(3))(C(8)H(10)N(4)O(2))(2)(H(2)O)], the Ag(I) atom is coordinated by two caffeine N atoms and, at longer distances, two O atoms of a coordinated water mol­ecule and the trifluoro­methane­sulfonate anion, resulting in an AgN(2)O(2) seesaw geometry. The caffeine mol­ecules are roughly coplanar [dihedral angle = 5.81 (5)°]. In the crystal, mol­ecules self-assemble into a linear supra­molecular chain along the c axis via O—H⋯O hydrogen bonds involving the coordinated water moledcule and carbonyl O atoms. The packing is consolidated by weak C—H⋯O inter­actions.