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Aqua(trifluoromethanesulfonato)bis(1,3,7-trimethylpurine-2,6-dione)silver(I)
In the title compound, [Ag(CF(3)SO(3))(C(8)H(10)N(4)O(2))(2)(H(2)O)], the Ag(I) atom is coordinated by two caffeine N atoms and, at longer distances, two O atoms of a coordinated water molecule and the trifluoromethanesulfonate anion, resulting in an AgN(2)O(2) seesaw geometry. The caffeine mole...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983140/ https://www.ncbi.nlm.nih.gov/pubmed/21587369 http://dx.doi.org/10.1107/S1600536810035300 |
Sumario: | In the title compound, [Ag(CF(3)SO(3))(C(8)H(10)N(4)O(2))(2)(H(2)O)], the Ag(I) atom is coordinated by two caffeine N atoms and, at longer distances, two O atoms of a coordinated water molecule and the trifluoromethanesulfonate anion, resulting in an AgN(2)O(2) seesaw geometry. The caffeine molecules are roughly coplanar [dihedral angle = 5.81 (5)°]. In the crystal, molecules self-assemble into a linear supramolecular chain along the c axis via O—H⋯O hydrogen bonds involving the coordinated water moledcule and carbonyl O atoms. The packing is consolidated by weak C—H⋯O interactions. |
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