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Aqua­(trifluoro­methane­sulfonato)­bis­(1,3,7-trimethyl­purine-2,6-dione)silver(I)

In the title compound, [Ag(CF(3)SO(3))(C(8)H(10)N(4)O(2))(2)(H(2)O)], the Ag(I) atom is coordinated by two caffeine N atoms and, at longer distances, two O atoms of a coordinated water mol­ecule and the trifluoro­methane­sulfonate anion, resulting in an AgN(2)O(2) seesaw geometry. The caffeine mol­e...

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Detalles Bibliográficos
Autores principales: Arman, Hadi D., Miller, Tyler, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983140/
https://www.ncbi.nlm.nih.gov/pubmed/21587369
http://dx.doi.org/10.1107/S1600536810035300
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author Arman, Hadi D.
Miller, Tyler
Tiekink, Edward R. T.
author_facet Arman, Hadi D.
Miller, Tyler
Tiekink, Edward R. T.
author_sort Arman, Hadi D.
collection PubMed
description In the title compound, [Ag(CF(3)SO(3))(C(8)H(10)N(4)O(2))(2)(H(2)O)], the Ag(I) atom is coordinated by two caffeine N atoms and, at longer distances, two O atoms of a coordinated water mol­ecule and the trifluoro­methane­sulfonate anion, resulting in an AgN(2)O(2) seesaw geometry. The caffeine mol­ecules are roughly coplanar [dihedral angle = 5.81 (5)°]. In the crystal, mol­ecules self-assemble into a linear supra­molecular chain along the c axis via O—H⋯O hydrogen bonds involving the coordinated water moledcule and carbonyl O atoms. The packing is consolidated by weak C—H⋯O inter­actions.
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spelling pubmed-29831402010-12-30 Aqua­(trifluoro­methane­sulfonato)­bis­(1,3,7-trimethyl­purine-2,6-dione)silver(I) Arman, Hadi D. Miller, Tyler Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(CF(3)SO(3))(C(8)H(10)N(4)O(2))(2)(H(2)O)], the Ag(I) atom is coordinated by two caffeine N atoms and, at longer distances, two O atoms of a coordinated water mol­ecule and the trifluoro­methane­sulfonate anion, resulting in an AgN(2)O(2) seesaw geometry. The caffeine mol­ecules are roughly coplanar [dihedral angle = 5.81 (5)°]. In the crystal, mol­ecules self-assemble into a linear supra­molecular chain along the c axis via O—H⋯O hydrogen bonds involving the coordinated water moledcule and carbonyl O atoms. The packing is consolidated by weak C—H⋯O inter­actions. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983140/ /pubmed/21587369 http://dx.doi.org/10.1107/S1600536810035300 Text en © Arman et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Arman, Hadi D.
Miller, Tyler
Tiekink, Edward R. T.
Aqua­(trifluoro­methane­sulfonato)­bis­(1,3,7-trimethyl­purine-2,6-dione)silver(I)
title Aqua­(trifluoro­methane­sulfonato)­bis­(1,3,7-trimethyl­purine-2,6-dione)silver(I)
title_full Aqua­(trifluoro­methane­sulfonato)­bis­(1,3,7-trimethyl­purine-2,6-dione)silver(I)
title_fullStr Aqua­(trifluoro­methane­sulfonato)­bis­(1,3,7-trimethyl­purine-2,6-dione)silver(I)
title_full_unstemmed Aqua­(trifluoro­methane­sulfonato)­bis­(1,3,7-trimethyl­purine-2,6-dione)silver(I)
title_short Aqua­(trifluoro­methane­sulfonato)­bis­(1,3,7-trimethyl­purine-2,6-dione)silver(I)
title_sort aqua­(trifluoro­methane­sulfonato)­bis­(1,3,7-trimethyl­purine-2,6-dione)silver(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983140/
https://www.ncbi.nlm.nih.gov/pubmed/21587369
http://dx.doi.org/10.1107/S1600536810035300
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