catena-Poly[hexaaqua-1κO,2κO,3κ(4) O-(μ(4)-3,5-dicarboxylatopyrazol-1-ido-3′:1:2:3κ(6) O (5):N (1),O (5′):N (2),O (3):O (3′))(μ(2)-3,5-dicarboxylatopyrazol-1-ido-1:2κ(4) N (2),O (3):N (1),O (5))-1,2-dicopper(II)-3-manganese(II)]

In the title compound, [Cu(2)Mn(C(5)HN(2)O(4))(2)(H(2)O)(6)](n), the Cu(II) ion is coordinated by two N atoms, two O atoms and one water O atom in a distorted square-pyramidal geometry. The Mn(II) ion is coordinated by two O atoms and four water O atoms in a distorted octa­hedral geometry. Two pyraz...

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Detalles Bibliográficos
Autor principal: Zhou, Xin-Hui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983142/
https://www.ncbi.nlm.nih.gov/pubmed/21587446
http://dx.doi.org/10.1107/S1600536810037542
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author Zhou, Xin-Hui
author_facet Zhou, Xin-Hui
author_sort Zhou, Xin-Hui
collection PubMed
description In the title compound, [Cu(2)Mn(C(5)HN(2)O(4))(2)(H(2)O)(6)](n), the Cu(II) ion is coordinated by two N atoms, two O atoms and one water O atom in a distorted square-pyramidal geometry. The Mn(II) ion is coordinated by two O atoms and four water O atoms in a distorted octa­hedral geometry. Two pyrazolyl-3,5-dicarboxyl­ate anions chelate to two copper ions, forming a dinuclear unit, which further connects the Mn(II )ions into chains extending along [100]. Both independent coordinated water mol­ecules on the Mn(II) ion are disordered in a 50:50 fashion.
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spelling pubmed-29831422010-12-30 catena-Poly[hexaaqua-1κO,2κO,3κ(4) O-(μ(4)-3,5-dicarboxylatopyrazol-1-ido-3′:1:2:3κ(6) O (5):N (1),O (5′):N (2),O (3):O (3′))(μ(2)-3,5-dicarboxylatopyrazol-1-ido-1:2κ(4) N (2),O (3):N (1),O (5))-1,2-dicopper(II)-3-manganese(II)] Zhou, Xin-Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)Mn(C(5)HN(2)O(4))(2)(H(2)O)(6)](n), the Cu(II) ion is coordinated by two N atoms, two O atoms and one water O atom in a distorted square-pyramidal geometry. The Mn(II) ion is coordinated by two O atoms and four water O atoms in a distorted octa­hedral geometry. Two pyrazolyl-3,5-dicarboxyl­ate anions chelate to two copper ions, forming a dinuclear unit, which further connects the Mn(II )ions into chains extending along [100]. Both independent coordinated water mol­ecules on the Mn(II) ion are disordered in a 50:50 fashion. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983142/ /pubmed/21587446 http://dx.doi.org/10.1107/S1600536810037542 Text en © Xin-Hui Zhou 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhou, Xin-Hui
catena-Poly[hexaaqua-1κO,2κO,3κ(4) O-(μ(4)-3,5-dicarboxylatopyrazol-1-ido-3′:1:2:3κ(6) O (5):N (1),O (5′):N (2),O (3):O (3′))(μ(2)-3,5-dicarboxylatopyrazol-1-ido-1:2κ(4) N (2),O (3):N (1),O (5))-1,2-dicopper(II)-3-manganese(II)]
title catena-Poly[hexaaqua-1κO,2κO,3κ(4) O-(μ(4)-3,5-dicarboxylatopyrazol-1-ido-3′:1:2:3κ(6) O (5):N (1),O (5′):N (2),O (3):O (3′))(μ(2)-3,5-dicarboxylatopyrazol-1-ido-1:2κ(4) N (2),O (3):N (1),O (5))-1,2-dicopper(II)-3-manganese(II)]
title_full catena-Poly[hexaaqua-1κO,2κO,3κ(4) O-(μ(4)-3,5-dicarboxylatopyrazol-1-ido-3′:1:2:3κ(6) O (5):N (1),O (5′):N (2),O (3):O (3′))(μ(2)-3,5-dicarboxylatopyrazol-1-ido-1:2κ(4) N (2),O (3):N (1),O (5))-1,2-dicopper(II)-3-manganese(II)]
title_fullStr catena-Poly[hexaaqua-1κO,2κO,3κ(4) O-(μ(4)-3,5-dicarboxylatopyrazol-1-ido-3′:1:2:3κ(6) O (5):N (1),O (5′):N (2),O (3):O (3′))(μ(2)-3,5-dicarboxylatopyrazol-1-ido-1:2κ(4) N (2),O (3):N (1),O (5))-1,2-dicopper(II)-3-manganese(II)]
title_full_unstemmed catena-Poly[hexaaqua-1κO,2κO,3κ(4) O-(μ(4)-3,5-dicarboxylatopyrazol-1-ido-3′:1:2:3κ(6) O (5):N (1),O (5′):N (2),O (3):O (3′))(μ(2)-3,5-dicarboxylatopyrazol-1-ido-1:2κ(4) N (2),O (3):N (1),O (5))-1,2-dicopper(II)-3-manganese(II)]
title_short catena-Poly[hexaaqua-1κO,2κO,3κ(4) O-(μ(4)-3,5-dicarboxylatopyrazol-1-ido-3′:1:2:3κ(6) O (5):N (1),O (5′):N (2),O (3):O (3′))(μ(2)-3,5-dicarboxylatopyrazol-1-ido-1:2κ(4) N (2),O (3):N (1),O (5))-1,2-dicopper(II)-3-manganese(II)]
title_sort catena-poly[hexaaqua-1κo,2κo,3κ(4) o-(μ(4)-3,5-dicarboxylatopyrazol-1-ido-3′:1:2:3κ(6) o (5):n (1),o (5′):n (2),o (3):o (3′))(μ(2)-3,5-dicarboxylatopyrazol-1-ido-1:2κ(4) n (2),o (3):n (1),o (5))-1,2-dicopper(ii)-3-manganese(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983142/
https://www.ncbi.nlm.nih.gov/pubmed/21587446
http://dx.doi.org/10.1107/S1600536810037542
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