(E)-1-(2,4,6-Trimeth­oxy­phen­yl)pent-1-en-3-one

The title compound, C(14)H(18)O(4), was obtained unintentionally as the major product of an attempted synthesis of (E,E)-2,5-bis­[2-(2,4,6-trimeth­oxy­phen­yl)ethen­yl]pyrazine. The crystal packing features layers based on two weak C—H⋯O hydrogen bonds involving the O atom of the carbonyl group and...

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Detalles Bibliográficos
Autores principales: Collas, Alain, Blockhuys, Frank
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983143/
https://www.ncbi.nlm.nih.gov/pubmed/21587519
http://dx.doi.org/10.1107/S1600536810034641
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author Collas, Alain
Blockhuys, Frank
author_facet Collas, Alain
Blockhuys, Frank
author_sort Collas, Alain
collection PubMed
description The title compound, C(14)H(18)O(4), was obtained unintentionally as the major product of an attempted synthesis of (E,E)-2,5-bis­[2-(2,4,6-trimeth­oxy­phen­yl)ethen­yl]pyrazine. The crystal packing features layers based on two weak C—H⋯O hydrogen bonds involving the O atom of the carbonyl group and two O(meth­oxy)⋯C(meth­oxy) inter­actions [3.109 (2) Å]. The sheets are inter­connected via meth­oxy–meth­oxy dimers and C—H⋯π inter­actions.
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spelling pubmed-29831432010-12-30 (E)-1-(2,4,6-Trimeth­oxy­phen­yl)pent-1-en-3-one Collas, Alain Blockhuys, Frank Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(18)O(4), was obtained unintentionally as the major product of an attempted synthesis of (E,E)-2,5-bis­[2-(2,4,6-trimeth­oxy­phen­yl)ethen­yl]pyrazine. The crystal packing features layers based on two weak C—H⋯O hydrogen bonds involving the O atom of the carbonyl group and two O(meth­oxy)⋯C(meth­oxy) inter­actions [3.109 (2) Å]. The sheets are inter­connected via meth­oxy–meth­oxy dimers and C—H⋯π inter­actions. International Union of Crystallography 2010-09-11 /pmc/articles/PMC2983143/ /pubmed/21587519 http://dx.doi.org/10.1107/S1600536810034641 Text en © Collas and Blockhuys 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Collas, Alain
Blockhuys, Frank
(E)-1-(2,4,6-Trimeth­oxy­phen­yl)pent-1-en-3-one
title (E)-1-(2,4,6-Trimeth­oxy­phen­yl)pent-1-en-3-one
title_full (E)-1-(2,4,6-Trimeth­oxy­phen­yl)pent-1-en-3-one
title_fullStr (E)-1-(2,4,6-Trimeth­oxy­phen­yl)pent-1-en-3-one
title_full_unstemmed (E)-1-(2,4,6-Trimeth­oxy­phen­yl)pent-1-en-3-one
title_short (E)-1-(2,4,6-Trimeth­oxy­phen­yl)pent-1-en-3-one
title_sort (e)-1-(2,4,6-trimeth­oxy­phen­yl)pent-1-en-3-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983143/
https://www.ncbi.nlm.nih.gov/pubmed/21587519
http://dx.doi.org/10.1107/S1600536810034641
work_keys_str_mv AT collasalain e1246trimethoxyphenylpent1en3one
AT blockhuysfrank e1246trimethoxyphenylpent1en3one

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