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Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II)
In the title compound, [CoCl(2)(C(14)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. The Co atom and the phenanthroline unit are located on a mirror plane. The methyl H atoms are dis...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983147/ https://www.ncbi.nlm.nih.gov/pubmed/21587388 http://dx.doi.org/10.1107/S1600536810035531 |
Sumario: | In the title compound, [CoCl(2)(C(14)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. The Co atom and the phenanthroline unit are located on a mirror plane. The methyl H atoms are disordered about the mirror plane and areeach half-occupied. In the crystal structure, π–π interactions between the pyridine and benzene rings and between the pyridine rings [centroid–centroid distances = 3.8821 (9) and 3.9502 (10) Å, respectively] stabilize the structure. |
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