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7-[(3,5-Di-tert-butyl-2-hy­droxy­benzyl­idene)amino]-4-methyl-2H-chromen-2-one

The title compound, C(25)H(29)NO(3), is a Schiff base derivative of coumarin 120. There are two structurally similar but crystallographically independent mol­ecules in the asymmetric unit. Both mol­ecules exist in E configurations with respect to the C=N double bonds. The dihedral angles between the...

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Detalles Bibliográficos
Autores principales: Aazam, Elham S., Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983148/
https://www.ncbi.nlm.nih.gov/pubmed/21587568
http://dx.doi.org/10.1107/S1600536810036743
Descripción
Sumario:The title compound, C(25)H(29)NO(3), is a Schiff base derivative of coumarin 120. There are two structurally similar but crystallographically independent mol­ecules in the asymmetric unit. Both mol­ecules exist in E configurations with respect to the C=N double bonds. The dihedral angles between the coumarin and 3,5-di-tert-butyl-2-hy­droxy­benzyl­idene ring planes are 4.62 (7) and 14.62 (7)° for the two mol­ecules. Intra­molecular O—H⋯N hydrogen bonding involving the O—H groups and the azomethine N atoms generate S(6) rings. In the crystal structure, independent mol­ecules are linked by C—H⋯π inter­actions, with groups of four mol­ecules stacked along the c axis.