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7-[(3,5-Di-tert-butyl-2-hydroxybenzylidene)amino]-4-methyl-2H-chromen-2-one
The title compound, C(25)H(29)NO(3), is a Schiff base derivative of coumarin 120. There are two structurally similar but crystallographically independent molecules in the asymmetric unit. Both molecules exist in E configurations with respect to the C=N double bonds. The dihedral angles between the...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983148/ https://www.ncbi.nlm.nih.gov/pubmed/21587568 http://dx.doi.org/10.1107/S1600536810036743 |
Sumario: | The title compound, C(25)H(29)NO(3), is a Schiff base derivative of coumarin 120. There are two structurally similar but crystallographically independent molecules in the asymmetric unit. Both molecules exist in E configurations with respect to the C=N double bonds. The dihedral angles between the coumarin and 3,5-di-tert-butyl-2-hydroxybenzylidene ring planes are 4.62 (7) and 14.62 (7)° for the two molecules. Intramolecular O—H⋯N hydrogen bonding involving the O—H groups and the azomethine N atoms generate S(6) rings. In the crystal structure, independent molecules are linked by C—H⋯π interactions, with groups of four molecules stacked along the c axis. |
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