Cargando…
{N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II)
In the title complex, [Cu(NCS)(2)(C(12)H(19)N(3))], the Cu(II) atom is five-coordinated in a square-pyramidal geometry defined by one pyridine N, one imine N, and one amine N atom of the tridentate Schiff base ligand and two N-bonded thiocyanate ions (one of the latter occupying the apical site). T...
| Autores principales: | , , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983150/ https://www.ncbi.nlm.nih.gov/pubmed/21587418 http://dx.doi.org/10.1107/S1600536810036378 |
| _version_ | 1782191812496064512 |
|---|---|
| author | Xue, Ling-Wei Zhao, Gan-Qing Han, Yong-Jun Chen, Li-Hua Peng, Qin-Long |
| author_facet | Xue, Ling-Wei Zhao, Gan-Qing Han, Yong-Jun Chen, Li-Hua Peng, Qin-Long |
| author_sort | Xue, Ling-Wei |
| collection | PubMed |
| description | In the title complex, [Cu(NCS)(2)(C(12)H(19)N(3))], the Cu(II) atom is five-coordinated in a square-pyramidal geometry defined by one pyridine N, one imine N, and one amine N atom of the tridentate Schiff base ligand and two N-bonded thiocyanate ions (one of the latter occupying the apical site). The three bridging C atoms and the two terminal C atoms of the Schiff base are disordered over two sets of sites, with occupancies of 0.465 (2) and 0.535 (2). |
| format | Text |
| id | pubmed-2983150 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29831502010-12-30 {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II) Xue, Ling-Wei Zhao, Gan-Qing Han, Yong-Jun Chen, Li-Hua Peng, Qin-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(NCS)(2)(C(12)H(19)N(3))], the Cu(II) atom is five-coordinated in a square-pyramidal geometry defined by one pyridine N, one imine N, and one amine N atom of the tridentate Schiff base ligand and two N-bonded thiocyanate ions (one of the latter occupying the apical site). The three bridging C atoms and the two terminal C atoms of the Schiff base are disordered over two sets of sites, with occupancies of 0.465 (2) and 0.535 (2). International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983150/ /pubmed/21587418 http://dx.doi.org/10.1107/S1600536810036378 Text en © Xue et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xue, Ling-Wei Zhao, Gan-Qing Han, Yong-Jun Chen, Li-Hua Peng, Qin-Long {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II) |
| title | {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II) |
| title_full | {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II) |
| title_fullStr | {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II) |
| title_full_unstemmed | {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II) |
| title_short | {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II) |
| title_sort | {n,n-dimethyl-n′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κn)copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983150/ https://www.ncbi.nlm.nih.gov/pubmed/21587418 http://dx.doi.org/10.1107/S1600536810036378 |
| work_keys_str_mv | AT xuelingwei nndimethyln12pyridylethylidenepropane13diaminebisthiocyanatokncopperii AT zhaoganqing nndimethyln12pyridylethylidenepropane13diaminebisthiocyanatokncopperii AT hanyongjun nndimethyln12pyridylethylidenepropane13diaminebisthiocyanatokncopperii AT chenlihua nndimethyln12pyridylethylidenepropane13diaminebisthiocyanatokncopperii AT pengqinlong nndimethyln12pyridylethylidenepropane13diaminebisthiocyanatokncopperii |