2,5-Bis(4-methyl­phen­yl)-4-oxopenta­noic acid

The title compound, C(19)H(20)O(3), was obtained from 1,4-bis­(4-methyl­phen­yl)but-3-yn-2-one in the presence of carbon monoxide by Ni(CN)(2) catalysis in a basic aqueous medium. Inter­molecular O—H⋯O hydrogen bonds lead to the formation of hydrogen-bonded carb­oxy­lic acid dimers [graph-set motif...

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Detalles Bibliográficos
Autores principales: Wang, Jun, Zhuang, Xiaomei, Hou, Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983153/
https://www.ncbi.nlm.nih.gov/pubmed/21587595
http://dx.doi.org/10.1107/S1600536810037323
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author Wang, Jun
Zhuang, Xiaomei
Hou, Yong
author_facet Wang, Jun
Zhuang, Xiaomei
Hou, Yong
author_sort Wang, Jun
collection PubMed
description The title compound, C(19)H(20)O(3), was obtained from 1,4-bis­(4-methyl­phen­yl)but-3-yn-2-one in the presence of carbon monoxide by Ni(CN)(2) catalysis in a basic aqueous medium. Inter­molecular O—H⋯O hydrogen bonds lead to the formation of hydrogen-bonded carb­oxy­lic acid dimers [graph-set motif R (2) (2)(8)]. Weak C—H⋯O hydrogen bonds between neighbouring dimers further extend the structure to give rise to a three-dimensional supra­molecular network.
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spelling pubmed-29831532010-12-30 2,5-Bis(4-methyl­phen­yl)-4-oxopenta­noic acid Wang, Jun Zhuang, Xiaomei Hou, Yong Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(20)O(3), was obtained from 1,4-bis­(4-methyl­phen­yl)but-3-yn-2-one in the presence of carbon monoxide by Ni(CN)(2) catalysis in a basic aqueous medium. Inter­molecular O—H⋯O hydrogen bonds lead to the formation of hydrogen-bonded carb­oxy­lic acid dimers [graph-set motif R (2) (2)(8)]. Weak C—H⋯O hydrogen bonds between neighbouring dimers further extend the structure to give rise to a three-dimensional supra­molecular network. International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983153/ /pubmed/21587595 http://dx.doi.org/10.1107/S1600536810037323 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Jun
Zhuang, Xiaomei
Hou, Yong
2,5-Bis(4-methyl­phen­yl)-4-oxopenta­noic acid
title 2,5-Bis(4-methyl­phen­yl)-4-oxopenta­noic acid
title_full 2,5-Bis(4-methyl­phen­yl)-4-oxopenta­noic acid
title_fullStr 2,5-Bis(4-methyl­phen­yl)-4-oxopenta­noic acid
title_full_unstemmed 2,5-Bis(4-methyl­phen­yl)-4-oxopenta­noic acid
title_short 2,5-Bis(4-methyl­phen­yl)-4-oxopenta­noic acid
title_sort 2,5-bis(4-methyl­phen­yl)-4-oxopenta­noic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983153/
https://www.ncbi.nlm.nih.gov/pubmed/21587595
http://dx.doi.org/10.1107/S1600536810037323
work_keys_str_mv AT wangjun 25bis4methylphenyl4oxopentanoicacid
AT zhuangxiaomei 25bis4methylphenyl4oxopentanoicacid
AT houyong 25bis4methylphenyl4oxopentanoicacid

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