Bis[2-(4-benzo­yloxy-2-hy­droxy­benzo­yl)-1-phenyl­ethenolato]diethano­lzinc(II)

The mononuclear title complex, [Zn(C(22)H(15)O(5))(2)(C(2)H(5)OH)(2)], contains a Zn(II) atom (site symmetry [Image: see text]) surrounded by six O atoms of the keto groups of two substituted 1,3-diketonate ligands and of two ethanol mol­ecules, resulting in a distorted octa­hedral coordination envi...

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Detalles Bibliográficos
Autores principales: Dong, Kai, Sun, Juan, Ruan, Ban-Feng, Gong, Hai-Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983159/
https://www.ncbi.nlm.nih.gov/pubmed/21587432
http://dx.doi.org/10.1107/S1600536810036202
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author Dong, Kai
Sun, Juan
Ruan, Ban-Feng
Gong, Hai-Bin
author_facet Dong, Kai
Sun, Juan
Ruan, Ban-Feng
Gong, Hai-Bin
author_sort Dong, Kai
collection PubMed
description The mononuclear title complex, [Zn(C(22)H(15)O(5))(2)(C(2)H(5)OH)(2)], contains a Zn(II) atom (site symmetry [Image: see text]) surrounded by six O atoms of the keto groups of two substituted 1,3-diketonate ligands and of two ethanol mol­ecules, resulting in a distorted octa­hedral coordination environment. The mol­ecular configuration is stabilized by an intra­molecular hydrogen bond between the phenolic hy­droxy group and the adjacent keto group. The hy­droxy group acts likewise as an acceptor of an inter­molecular O—H⋯O hydrogen bond with the hy­droxy group of the ethanol mol­ecule as the donor. The hydrogen-bonding scheme leads to the formation of supra­molecular layers parallel to (010).
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spelling pubmed-29831592010-12-30 Bis[2-(4-benzo­yloxy-2-hy­droxy­benzo­yl)-1-phenyl­ethenolato]diethano­lzinc(II) Dong, Kai Sun, Juan Ruan, Ban-Feng Gong, Hai-Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mononuclear title complex, [Zn(C(22)H(15)O(5))(2)(C(2)H(5)OH)(2)], contains a Zn(II) atom (site symmetry [Image: see text]) surrounded by six O atoms of the keto groups of two substituted 1,3-diketonate ligands and of two ethanol mol­ecules, resulting in a distorted octa­hedral coordination environment. The mol­ecular configuration is stabilized by an intra­molecular hydrogen bond between the phenolic hy­droxy group and the adjacent keto group. The hy­droxy group acts likewise as an acceptor of an inter­molecular O—H⋯O hydrogen bond with the hy­droxy group of the ethanol mol­ecule as the donor. The hydrogen-bonding scheme leads to the formation of supra­molecular layers parallel to (010). International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983159/ /pubmed/21587432 http://dx.doi.org/10.1107/S1600536810036202 Text en © Dong et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dong, Kai
Sun, Juan
Ruan, Ban-Feng
Gong, Hai-Bin
Bis[2-(4-benzo­yloxy-2-hy­droxy­benzo­yl)-1-phenyl­ethenolato]diethano­lzinc(II)
title Bis[2-(4-benzo­yloxy-2-hy­droxy­benzo­yl)-1-phenyl­ethenolato]diethano­lzinc(II)
title_full Bis[2-(4-benzo­yloxy-2-hy­droxy­benzo­yl)-1-phenyl­ethenolato]diethano­lzinc(II)
title_fullStr Bis[2-(4-benzo­yloxy-2-hy­droxy­benzo­yl)-1-phenyl­ethenolato]diethano­lzinc(II)
title_full_unstemmed Bis[2-(4-benzo­yloxy-2-hy­droxy­benzo­yl)-1-phenyl­ethenolato]diethano­lzinc(II)
title_short Bis[2-(4-benzo­yloxy-2-hy­droxy­benzo­yl)-1-phenyl­ethenolato]diethano­lzinc(II)
title_sort bis[2-(4-benzo­yloxy-2-hy­droxy­benzo­yl)-1-phenyl­ethenolato]diethano­lzinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983159/
https://www.ncbi.nlm.nih.gov/pubmed/21587432
http://dx.doi.org/10.1107/S1600536810036202
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AT sunjuan bis24benzoyloxy2hydroxybenzoyl1phenylethenolatodiethanolzincii
AT ruanbanfeng bis24benzoyloxy2hydroxybenzoyl1phenylethenolatodiethanolzincii
AT gonghaibin bis24benzoyloxy2hydroxybenzoyl1phenylethenolatodiethanolzincii

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