1-(4-Fluoro­phen­yl)biguanid-1-ium chloride

The title compound, C(8)H(11)FN(5) (+)·Cl(−), crystallized with a monoprotonated 1-(4-fluoro­phen­yl)biguanidinium cation and a chloride anion in the asymmetric unit. The biguanidium group is not planar [dihedral angle between the two CN(3) groups = 52.0 (1)°] and is rotated with respect to the phen...

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Detalles Bibliográficos
Autores principales: Tutughamiarso, Maya, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983160/
https://www.ncbi.nlm.nih.gov/pubmed/21587619
http://dx.doi.org/10.1107/S1600536810037785
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author Tutughamiarso, Maya
Bolte, Michael
author_facet Tutughamiarso, Maya
Bolte, Michael
author_sort Tutughamiarso, Maya
collection PubMed
description The title compound, C(8)H(11)FN(5) (+)·Cl(−), crystallized with a monoprotonated 1-(4-fluoro­phen­yl)biguanidinium cation and a chloride anion in the asymmetric unit. The biguanidium group is not planar [dihedral angle between the two CN(3) groups = 52.0 (1)°] and is rotated with respect to the phenyl group [τ = 54.3 (3)°]. In the crystal, N—H⋯N hydrogen-bonded centrosymmetric dimers are connected into ribbons, which are further stabilized by N—H⋯Cl interactions, forming a three-dimensional hydrogen-bonded network.
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spelling pubmed-29831602010-12-30 1-(4-Fluoro­phen­yl)biguanid-1-ium chloride Tutughamiarso, Maya Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(8)H(11)FN(5) (+)·Cl(−), crystallized with a monoprotonated 1-(4-fluoro­phen­yl)biguanidinium cation and a chloride anion in the asymmetric unit. The biguanidium group is not planar [dihedral angle between the two CN(3) groups = 52.0 (1)°] and is rotated with respect to the phenyl group [τ = 54.3 (3)°]. In the crystal, N—H⋯N hydrogen-bonded centrosymmetric dimers are connected into ribbons, which are further stabilized by N—H⋯Cl interactions, forming a three-dimensional hydrogen-bonded network. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983160/ /pubmed/21587619 http://dx.doi.org/10.1107/S1600536810037785 Text en © Tutughamiarso and Bolte 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tutughamiarso, Maya
Bolte, Michael
1-(4-Fluoro­phen­yl)biguanid-1-ium chloride
title 1-(4-Fluoro­phen­yl)biguanid-1-ium chloride
title_full 1-(4-Fluoro­phen­yl)biguanid-1-ium chloride
title_fullStr 1-(4-Fluoro­phen­yl)biguanid-1-ium chloride
title_full_unstemmed 1-(4-Fluoro­phen­yl)biguanid-1-ium chloride
title_short 1-(4-Fluoro­phen­yl)biguanid-1-ium chloride
title_sort 1-(4-fluoro­phen­yl)biguanid-1-ium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983160/
https://www.ncbi.nlm.nih.gov/pubmed/21587619
http://dx.doi.org/10.1107/S1600536810037785
work_keys_str_mv AT tutughamiarsomaya 14fluorophenylbiguanid1iumchloride
AT boltemichael 14fluorophenylbiguanid1iumchloride

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