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Bis[5-(2-pyridyl)pyrazine-2-carbonitrile]silver(I) tetrafluoridoborate
In the title mononuclear complex, [Ag(C(10)H(6)N(4))(2)]BF(4), the Ag(I) atom adopts a square-planar N(4 )coordination geometry and is surrounded by two 5-(2-pyridyl)pyrazine-2-carbonitrile ligands. The tetrafluoridoborate anions link the mononuclear cations through intermolecular C—H⋯F hydrogen...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983161/ https://www.ncbi.nlm.nih.gov/pubmed/21587386 http://dx.doi.org/10.1107/S1600536810035178 |
Sumario: | In the title mononuclear complex, [Ag(C(10)H(6)N(4))(2)]BF(4), the Ag(I) atom adopts a square-planar N(4 )coordination geometry and is surrounded by two 5-(2-pyridyl)pyrazine-2-carbonitrile ligands. The tetrafluoridoborate anions link the mononuclear cations through intermolecular C—H⋯F hydrogen-bonding interactions, forming an infinite tape structure along [110]. Other weak interactions occur: π–π stacking with centroid–centroid distances of 3.820 (2) and 3.898 (1) Å between pyridyl rings and 3.610 (2) and 3.926 (2) Å between pyrazinyl rings as well as F⋯π contacts involving the tetrafluoridoborate anions and pyrazine rings [F⋯centroid = 2.999 (3) Å]; these combine with the hydrogen-bonding interactions to link the mononuclear cations into a three-dimensional supramolecular architecture. |
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