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Bis[5-(2-pyridyl)pyrazine-2-carbonitrile]silver(I) tetrafluoridoborate
In the title mononuclear complex, [Ag(C(10)H(6)N(4))(2)]BF(4), the Ag(I) atom adopts a square-planar N(4 )coordination geometry and is surrounded by two 5-(2-pyridyl)pyrazine-2-carbonitrile ligands. The tetrafluoridoborate anions link the mononuclear cations through intermolecular C—H⋯F hydrogen...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983161/ https://www.ncbi.nlm.nih.gov/pubmed/21587386 http://dx.doi.org/10.1107/S1600536810035178 |
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author | Wang, Zi-Jia Zhang, Fan Wan, Chong-Qing |
author_facet | Wang, Zi-Jia Zhang, Fan Wan, Chong-Qing |
author_sort | Wang, Zi-Jia |
collection | PubMed |
description | In the title mononuclear complex, [Ag(C(10)H(6)N(4))(2)]BF(4), the Ag(I) atom adopts a square-planar N(4 )coordination geometry and is surrounded by two 5-(2-pyridyl)pyrazine-2-carbonitrile ligands. The tetrafluoridoborate anions link the mononuclear cations through intermolecular C—H⋯F hydrogen-bonding interactions, forming an infinite tape structure along [110]. Other weak interactions occur: π–π stacking with centroid–centroid distances of 3.820 (2) and 3.898 (1) Å between pyridyl rings and 3.610 (2) and 3.926 (2) Å between pyrazinyl rings as well as F⋯π contacts involving the tetrafluoridoborate anions and pyrazine rings [F⋯centroid = 2.999 (3) Å]; these combine with the hydrogen-bonding interactions to link the mononuclear cations into a three-dimensional supramolecular architecture. |
format | Text |
id | pubmed-2983161 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29831612010-12-30 Bis[5-(2-pyridyl)pyrazine-2-carbonitrile]silver(I) tetrafluoridoborate Wang, Zi-Jia Zhang, Fan Wan, Chong-Qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Ag(C(10)H(6)N(4))(2)]BF(4), the Ag(I) atom adopts a square-planar N(4 )coordination geometry and is surrounded by two 5-(2-pyridyl)pyrazine-2-carbonitrile ligands. The tetrafluoridoborate anions link the mononuclear cations through intermolecular C—H⋯F hydrogen-bonding interactions, forming an infinite tape structure along [110]. Other weak interactions occur: π–π stacking with centroid–centroid distances of 3.820 (2) and 3.898 (1) Å between pyridyl rings and 3.610 (2) and 3.926 (2) Å between pyrazinyl rings as well as F⋯π contacts involving the tetrafluoridoborate anions and pyrazine rings [F⋯centroid = 2.999 (3) Å]; these combine with the hydrogen-bonding interactions to link the mononuclear cations into a three-dimensional supramolecular architecture. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983161/ /pubmed/21587386 http://dx.doi.org/10.1107/S1600536810035178 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Zi-Jia Zhang, Fan Wan, Chong-Qing Bis[5-(2-pyridyl)pyrazine-2-carbonitrile]silver(I) tetrafluoridoborate |
title | Bis[5-(2-pyridyl)pyrazine-2-carbonitrile]silver(I) tetrafluoridoborate |
title_full | Bis[5-(2-pyridyl)pyrazine-2-carbonitrile]silver(I) tetrafluoridoborate |
title_fullStr | Bis[5-(2-pyridyl)pyrazine-2-carbonitrile]silver(I) tetrafluoridoborate |
title_full_unstemmed | Bis[5-(2-pyridyl)pyrazine-2-carbonitrile]silver(I) tetrafluoridoborate |
title_short | Bis[5-(2-pyridyl)pyrazine-2-carbonitrile]silver(I) tetrafluoridoborate |
title_sort | bis[5-(2-pyridyl)pyrazine-2-carbonitrile]silver(i) tetrafluoridoborate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983161/ https://www.ncbi.nlm.nih.gov/pubmed/21587386 http://dx.doi.org/10.1107/S1600536810035178 |
work_keys_str_mv | AT wangzijia bis52pyridylpyrazine2carbonitrilesilveritetrafluoridoborate AT zhangfan bis52pyridylpyrazine2carbonitrilesilveritetrafluoridoborate AT wanchongqing bis52pyridylpyrazine2carbonitrilesilveritetrafluoridoborate |