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Bis[5-(2-pyrid­yl)pyrazine-2-carbonitrile]­silver(I) tetra­fluorido­borate

In the title mononuclear complex, [Ag(C(10)H(6)N(4))(2)]BF(4), the Ag(I) atom adopts a square-planar N(4 )coordination geometry and is surrounded by two 5-(2-pyrid­yl)pyrazine-2-carbonitrile ligands. The tetra­fluorido­borate anions link the mononuclear cations through inter­molecular C—H⋯F hydrogen...

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Detalles Bibliográficos
Autores principales: Wang, Zi-Jia, Zhang, Fan, Wan, Chong-Qing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983161/
https://www.ncbi.nlm.nih.gov/pubmed/21587386
http://dx.doi.org/10.1107/S1600536810035178
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author Wang, Zi-Jia
Zhang, Fan
Wan, Chong-Qing
author_facet Wang, Zi-Jia
Zhang, Fan
Wan, Chong-Qing
author_sort Wang, Zi-Jia
collection PubMed
description In the title mononuclear complex, [Ag(C(10)H(6)N(4))(2)]BF(4), the Ag(I) atom adopts a square-planar N(4 )coordination geometry and is surrounded by two 5-(2-pyrid­yl)pyrazine-2-carbonitrile ligands. The tetra­fluorido­borate anions link the mononuclear cations through inter­molecular C—H⋯F hydrogen-bonding inter­actions, forming an infinite tape structure along [110]. Other weak inter­actions occur: π–π stacking with centroid–centroid distances of 3.820 (2) and 3.898 (1) Å between pyridyl rings and 3.610 (2) and 3.926 (2) Å between pyrazinyl rings as well as F⋯π contacts involving the tetra­fluorido­borate anions and pyrazine rings [F⋯centroid = 2.999 (3) Å]; these combine with the hydrogen-bonding inter­actions to link the mononuclear cations into a three-dimensional supra­molecular architecture.
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spelling pubmed-29831612010-12-30 Bis[5-(2-pyrid­yl)pyrazine-2-carbonitrile]­silver(I) tetra­fluorido­borate Wang, Zi-Jia Zhang, Fan Wan, Chong-Qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Ag(C(10)H(6)N(4))(2)]BF(4), the Ag(I) atom adopts a square-planar N(4 )coordination geometry and is surrounded by two 5-(2-pyrid­yl)pyrazine-2-carbonitrile ligands. The tetra­fluorido­borate anions link the mononuclear cations through inter­molecular C—H⋯F hydrogen-bonding inter­actions, forming an infinite tape structure along [110]. Other weak inter­actions occur: π–π stacking with centroid–centroid distances of 3.820 (2) and 3.898 (1) Å between pyridyl rings and 3.610 (2) and 3.926 (2) Å between pyrazinyl rings as well as F⋯π contacts involving the tetra­fluorido­borate anions and pyrazine rings [F⋯centroid = 2.999 (3) Å]; these combine with the hydrogen-bonding inter­actions to link the mononuclear cations into a three-dimensional supra­molecular architecture. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983161/ /pubmed/21587386 http://dx.doi.org/10.1107/S1600536810035178 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Zi-Jia
Zhang, Fan
Wan, Chong-Qing
Bis[5-(2-pyrid­yl)pyrazine-2-carbonitrile]­silver(I) tetra­fluorido­borate
title Bis[5-(2-pyrid­yl)pyrazine-2-carbonitrile]­silver(I) tetra­fluorido­borate
title_full Bis[5-(2-pyrid­yl)pyrazine-2-carbonitrile]­silver(I) tetra­fluorido­borate
title_fullStr Bis[5-(2-pyrid­yl)pyrazine-2-carbonitrile]­silver(I) tetra­fluorido­borate
title_full_unstemmed Bis[5-(2-pyrid­yl)pyrazine-2-carbonitrile]­silver(I) tetra­fluorido­borate
title_short Bis[5-(2-pyrid­yl)pyrazine-2-carbonitrile]­silver(I) tetra­fluorido­borate
title_sort bis[5-(2-pyrid­yl)pyrazine-2-carbonitrile]­silver(i) tetra­fluorido­borate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983161/
https://www.ncbi.nlm.nih.gov/pubmed/21587386
http://dx.doi.org/10.1107/S1600536810035178
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