2-Amino-4,6-dimethyl­pyridinium benzoate

In the title compound, C(7)H(11)N(2) (+)·C(7)H(5)O(2) (−), the 2-amino-4,6-dimethyl­pyridinium cation and the benzoate anion are linked by two N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The H atoms in both the methyl groups are rotationally disordered, with fixed site occupancies of 0...

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Detalles Bibliográficos
Autores principales: Asaruddin, Mohd Razip, Wahab, Habibah A, Mohamed, Nornisah, Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983164/
https://www.ncbi.nlm.nih.gov/pubmed/21587493
http://dx.doi.org/10.1107/S1600536810034811
Descripción
Sumario:In the title compound, C(7)H(11)N(2) (+)·C(7)H(5)O(2) (−), the 2-amino-4,6-dimethyl­pyridinium cation and the benzoate anion are linked by two N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The H atoms in both the methyl groups are rotationally disordered, with fixed site occupancies of 0.50. In the crystal structure, the mol­ecules are stabilized by inter­molecular N—H⋯O hydrogen bonds. A π–π inter­action, with a centroid–centroid distance of 3.661 (2) Å, is also observed.

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