2-Amino-4,6-dimethyl­pyridinium benzoate

In the title compound, C(7)H(11)N(2) (+)·C(7)H(5)O(2) (−), the 2-amino-4,6-dimethyl­pyridinium cation and the benzoate anion are linked by two N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The H atoms in both the methyl groups are rotationally disordered, with fixed site occupancies of 0...

Descripción completa

Detalles Bibliográficos
Autores principales: Asaruddin, Mohd Razip, Wahab, Habibah A, Mohamed, Nornisah, Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983164/
https://www.ncbi.nlm.nih.gov/pubmed/21587493
http://dx.doi.org/10.1107/S1600536810034811
_version_ 1782191815817953280
author Asaruddin, Mohd Razip
Wahab, Habibah A
Mohamed, Nornisah
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_facet Asaruddin, Mohd Razip
Wahab, Habibah A
Mohamed, Nornisah
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_sort Asaruddin, Mohd Razip
collection PubMed
description In the title compound, C(7)H(11)N(2) (+)·C(7)H(5)O(2) (−), the 2-amino-4,6-dimethyl­pyridinium cation and the benzoate anion are linked by two N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The H atoms in both the methyl groups are rotationally disordered, with fixed site occupancies of 0.50. In the crystal structure, the mol­ecules are stabilized by inter­molecular N—H⋯O hydrogen bonds. A π–π inter­action, with a centroid–centroid distance of 3.661 (2) Å, is also observed.
format Text
id pubmed-2983164
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29831642010-12-30 2-Amino-4,6-dimethyl­pyridinium benzoate Asaruddin, Mohd Razip Wahab, Habibah A Mohamed, Nornisah Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(11)N(2) (+)·C(7)H(5)O(2) (−), the 2-amino-4,6-dimethyl­pyridinium cation and the benzoate anion are linked by two N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The H atoms in both the methyl groups are rotationally disordered, with fixed site occupancies of 0.50. In the crystal structure, the mol­ecules are stabilized by inter­molecular N—H⋯O hydrogen bonds. A π–π inter­action, with a centroid–centroid distance of 3.661 (2) Å, is also observed. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983164/ /pubmed/21587493 http://dx.doi.org/10.1107/S1600536810034811 Text en © Asaruddin et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asaruddin, Mohd Razip
Wahab, Habibah A
Mohamed, Nornisah
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
2-Amino-4,6-dimethyl­pyridinium benzoate
title 2-Amino-4,6-dimethyl­pyridinium benzoate
title_full 2-Amino-4,6-dimethyl­pyridinium benzoate
title_fullStr 2-Amino-4,6-dimethyl­pyridinium benzoate
title_full_unstemmed 2-Amino-4,6-dimethyl­pyridinium benzoate
title_short 2-Amino-4,6-dimethyl­pyridinium benzoate
title_sort 2-amino-4,6-dimethyl­pyridinium benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983164/
https://www.ncbi.nlm.nih.gov/pubmed/21587493
http://dx.doi.org/10.1107/S1600536810034811
work_keys_str_mv AT asaruddinmohdrazip 2amino46dimethylpyridiniumbenzoate
AT wahabhabibaha 2amino46dimethylpyridiniumbenzoate
AT mohamednornisah 2amino46dimethylpyridiniumbenzoate
AT roslimohdmustaqim 2amino46dimethylpyridiniumbenzoate
AT funhoongkun 2amino46dimethylpyridiniumbenzoate

Ejemplares similares