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2-Phenylacetic acid–3-{(E)-2-[(E)-pyridin-3-ylmethylidene]hydrazin-1-ylidenemethyl}pyridine (2/1)
The asymmetric unit of the title 1:2 adduct, C(12)H(10)N(4)·2C(8)H(8)O(2), comprises a single molecule of 2-phenylacetic acid and half a molecule of 3-pyridinealdazine; the latter is completed by crystallographic inversion symmetry. In the crystal, molecules are connected into a three-component...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983166/ https://www.ncbi.nlm.nih.gov/pubmed/21587652 http://dx.doi.org/10.1107/S1600536810038390 |
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author | Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. |
author_facet | Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. |
author_sort | Arman, Hadi D. |
collection | PubMed |
description | The asymmetric unit of the title 1:2 adduct, C(12)H(10)N(4)·2C(8)H(8)O(2), comprises a single molecule of 2-phenylacetic acid and half a molecule of 3-pyridinealdazine; the latter is completed by crystallographic inversion symmetry. In the crystal, molecules are connected into a three-component aggregate via O—H⋯N hydrogen bonds. As the carboxyl group lies above the plane through the benzene ring to which it is attached [C—C—C—C = 62.24 (17)°] and the 4-pyridinealdazine molecule is almost planar (r.m.s. deviation of the 16 non-H atoms = 0.027 Å), the overall shape of the aggregate is that of a flattened extended chair. Layers of these aggregates are connected by C—H⋯O and C—H⋯π interactions and stack parallel to (220). |
format | Text |
id | pubmed-2983166 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29831662010-12-30 2-Phenylacetic acid–3-{(E)-2-[(E)-pyridin-3-ylmethylidene]hydrazin-1-ylidenemethyl}pyridine (2/1) Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title 1:2 adduct, C(12)H(10)N(4)·2C(8)H(8)O(2), comprises a single molecule of 2-phenylacetic acid and half a molecule of 3-pyridinealdazine; the latter is completed by crystallographic inversion symmetry. In the crystal, molecules are connected into a three-component aggregate via O—H⋯N hydrogen bonds. As the carboxyl group lies above the plane through the benzene ring to which it is attached [C—C—C—C = 62.24 (17)°] and the 4-pyridinealdazine molecule is almost planar (r.m.s. deviation of the 16 non-H atoms = 0.027 Å), the overall shape of the aggregate is that of a flattened extended chair. Layers of these aggregates are connected by C—H⋯O and C—H⋯π interactions and stack parallel to (220). International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983166/ /pubmed/21587652 http://dx.doi.org/10.1107/S1600536810038390 Text en © Arman et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. 2-Phenylacetic acid–3-{(E)-2-[(E)-pyridin-3-ylmethylidene]hydrazin-1-ylidenemethyl}pyridine (2/1) |
title | 2-Phenylacetic acid–3-{(E)-2-[(E)-pyridin-3-ylmethylidene]hydrazin-1-ylidenemethyl}pyridine (2/1) |
title_full | 2-Phenylacetic acid–3-{(E)-2-[(E)-pyridin-3-ylmethylidene]hydrazin-1-ylidenemethyl}pyridine (2/1) |
title_fullStr | 2-Phenylacetic acid–3-{(E)-2-[(E)-pyridin-3-ylmethylidene]hydrazin-1-ylidenemethyl}pyridine (2/1) |
title_full_unstemmed | 2-Phenylacetic acid–3-{(E)-2-[(E)-pyridin-3-ylmethylidene]hydrazin-1-ylidenemethyl}pyridine (2/1) |
title_short | 2-Phenylacetic acid–3-{(E)-2-[(E)-pyridin-3-ylmethylidene]hydrazin-1-ylidenemethyl}pyridine (2/1) |
title_sort | 2-phenylacetic acid–3-{(e)-2-[(e)-pyridin-3-ylmethylidene]hydrazin-1-ylidenemethyl}pyridine (2/1) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983166/ https://www.ncbi.nlm.nih.gov/pubmed/21587652 http://dx.doi.org/10.1107/S1600536810038390 |
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