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Aqua(9,10-dioxoanthracene-1,5-disulfonato-κO (1))bis(1,10-phenanthroline-κ(2) N,N′)nickel(II)
In the mononuclear title complex, [Ni(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)], the Ni(II) atom is in a distorted octahedral coordination formed by four N atoms from two chelating 1,10-phenanthroline ligands and by two O atoms, one from a 9,10-dioxoanthracene-1,5-disulfonate ligand and the othe...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983167/ https://www.ncbi.nlm.nih.gov/pubmed/21587353 http://dx.doi.org/10.1107/S1600536810034252 |
Sumario: | In the mononuclear title complex, [Ni(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)], the Ni(II) atom is in a distorted octahedral coordination formed by four N atoms from two chelating 1,10-phenanthroline ligands and by two O atoms, one from a 9,10-dioxoanthracene-1,5-disulfonate ligand and the other from a water molecule. An intramolecular O—H⋯O hydrogen bond occurs. In the crystal, intermolecular O—H⋯O hydrogen bonds link the mononuclear complexes into chains extending parallel to [010]. Furthermore, π–π stacking interactions [centroid–centroid distance = 3.5696 (6) Å] stabilize the crystal structuure. |
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