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Aqua(9,10-dioxoanthracene-1,5-disulfonato-κO (1))bis(1,10-phenanthroline-κ(2) N,N′)nickel(II)
In the mononuclear title complex, [Ni(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)], the Ni(II) atom is in a distorted octahedral coordination formed by four N atoms from two chelating 1,10-phenanthroline ligands and by two O atoms, one from a 9,10-dioxoanthracene-1,5-disulfonate ligand and the othe...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983167/ https://www.ncbi.nlm.nih.gov/pubmed/21587353 http://dx.doi.org/10.1107/S1600536810034252 |
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author | Cao, Ying-Yu |
author_facet | Cao, Ying-Yu |
author_sort | Cao, Ying-Yu |
collection | PubMed |
description | In the mononuclear title complex, [Ni(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)], the Ni(II) atom is in a distorted octahedral coordination formed by four N atoms from two chelating 1,10-phenanthroline ligands and by two O atoms, one from a 9,10-dioxoanthracene-1,5-disulfonate ligand and the other from a water molecule. An intramolecular O—H⋯O hydrogen bond occurs. In the crystal, intermolecular O—H⋯O hydrogen bonds link the mononuclear complexes into chains extending parallel to [010]. Furthermore, π–π stacking interactions [centroid–centroid distance = 3.5696 (6) Å] stabilize the crystal structuure. |
format | Text |
id | pubmed-2983167 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29831672010-12-30 Aqua(9,10-dioxoanthracene-1,5-disulfonato-κO (1))bis(1,10-phenanthroline-κ(2) N,N′)nickel(II) Cao, Ying-Yu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Ni(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)], the Ni(II) atom is in a distorted octahedral coordination formed by four N atoms from two chelating 1,10-phenanthroline ligands and by two O atoms, one from a 9,10-dioxoanthracene-1,5-disulfonate ligand and the other from a water molecule. An intramolecular O—H⋯O hydrogen bond occurs. In the crystal, intermolecular O—H⋯O hydrogen bonds link the mononuclear complexes into chains extending parallel to [010]. Furthermore, π–π stacking interactions [centroid–centroid distance = 3.5696 (6) Å] stabilize the crystal structuure. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983167/ /pubmed/21587353 http://dx.doi.org/10.1107/S1600536810034252 Text en © Ying-Yu Cao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Cao, Ying-Yu Aqua(9,10-dioxoanthracene-1,5-disulfonato-κO (1))bis(1,10-phenanthroline-κ(2) N,N′)nickel(II) |
title | Aqua(9,10-dioxoanthracene-1,5-disulfonato-κO
(1))bis(1,10-phenanthroline-κ(2)
N,N′)nickel(II) |
title_full | Aqua(9,10-dioxoanthracene-1,5-disulfonato-κO
(1))bis(1,10-phenanthroline-κ(2)
N,N′)nickel(II) |
title_fullStr | Aqua(9,10-dioxoanthracene-1,5-disulfonato-κO
(1))bis(1,10-phenanthroline-κ(2)
N,N′)nickel(II) |
title_full_unstemmed | Aqua(9,10-dioxoanthracene-1,5-disulfonato-κO
(1))bis(1,10-phenanthroline-κ(2)
N,N′)nickel(II) |
title_short | Aqua(9,10-dioxoanthracene-1,5-disulfonato-κO
(1))bis(1,10-phenanthroline-κ(2)
N,N′)nickel(II) |
title_sort | aqua(9,10-dioxoanthracene-1,5-disulfonato-κo
(1))bis(1,10-phenanthroline-κ(2)
n,n′)nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983167/ https://www.ncbi.nlm.nih.gov/pubmed/21587353 http://dx.doi.org/10.1107/S1600536810034252 |
work_keys_str_mv | AT caoyingyu aqua910dioxoanthracene15disulfonatoko1bis110phenanthrolinek2nnnickelii |