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Aqua­(9,10-dioxoanthracene-1,5-disul­fonato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II)

In the mononuclear title complex, [Ni(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)], the Ni(II) atom is in a distorted octa­hedral coordination formed by four N atoms from two chelating 1,10-phenanthroline ligands and by two O atoms, one from a 9,10-dioxoanthracene-1,5-disulfonate ligand and the othe...

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Detalles Bibliográficos
Autor principal: Cao, Ying-Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983167/
https://www.ncbi.nlm.nih.gov/pubmed/21587353
http://dx.doi.org/10.1107/S1600536810034252
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author Cao, Ying-Yu
author_facet Cao, Ying-Yu
author_sort Cao, Ying-Yu
collection PubMed
description In the mononuclear title complex, [Ni(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)], the Ni(II) atom is in a distorted octa­hedral coordination formed by four N atoms from two chelating 1,10-phenanthroline ligands and by two O atoms, one from a 9,10-dioxoanthracene-1,5-disulfonate ligand and the other from a water mol­ecule. An intra­molecular O—H⋯O hydrogen bond occurs. In the crystal, inter­molecular O—H⋯O hydrogen bonds link the mononuclear complexes into chains extending parallel to [010]. Furthermore, π–π stacking inter­actions [centroid–centroid distance = 3.5696 (6) Å] stabilize the crystal structuure.
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spelling pubmed-29831672010-12-30 Aqua­(9,10-dioxoanthracene-1,5-disul­fonato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II) Cao, Ying-Yu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Ni(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)], the Ni(II) atom is in a distorted octa­hedral coordination formed by four N atoms from two chelating 1,10-phenanthroline ligands and by two O atoms, one from a 9,10-dioxoanthracene-1,5-disulfonate ligand and the other from a water mol­ecule. An intra­molecular O—H⋯O hydrogen bond occurs. In the crystal, inter­molecular O—H⋯O hydrogen bonds link the mononuclear complexes into chains extending parallel to [010]. Furthermore, π–π stacking inter­actions [centroid–centroid distance = 3.5696 (6) Å] stabilize the crystal structuure. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983167/ /pubmed/21587353 http://dx.doi.org/10.1107/S1600536810034252 Text en © Ying-Yu Cao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cao, Ying-Yu
Aqua­(9,10-dioxoanthracene-1,5-disul­fonato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title Aqua­(9,10-dioxoanthracene-1,5-disul­fonato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title_full Aqua­(9,10-dioxoanthracene-1,5-disul­fonato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title_fullStr Aqua­(9,10-dioxoanthracene-1,5-disul­fonato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title_full_unstemmed Aqua­(9,10-dioxoanthracene-1,5-disul­fonato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title_short Aqua­(9,10-dioxoanthracene-1,5-disul­fonato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title_sort aqua­(9,10-dioxoanthracene-1,5-disul­fonato-κo (1))bis­(1,10-phenanthroline-κ(2) n,n′)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983167/
https://www.ncbi.nlm.nih.gov/pubmed/21587353
http://dx.doi.org/10.1107/S1600536810034252
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