4-[(2-Hy­droxy-5-nitro­benzyl­idene)amino]­benzene­sulfonamide

The title Schiff base compound, C(13)H(11)N(3)O(5)S, exists in an E configuration with respect to the C=N double bond. The benzene rings are almost coplanar, making a dihedral angle of 2.82 (6). The sulfonamide group is twisted away from the attached phenyl ring with an N—S—C—C torsion angle of 64.8...

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Detalles Bibliográficos
Autores principales: Tan, Yi-Han, Teoh, Siang Guan, Loh, Wan-Sin, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983168/
https://www.ncbi.nlm.nih.gov/pubmed/21587586
http://dx.doi.org/10.1107/S1600536810036949
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author Tan, Yi-Han
Teoh, Siang Guan
Loh, Wan-Sin
Fun, Hoong-Kun
author_facet Tan, Yi-Han
Teoh, Siang Guan
Loh, Wan-Sin
Fun, Hoong-Kun
author_sort Tan, Yi-Han
collection PubMed
description The title Schiff base compound, C(13)H(11)N(3)O(5)S, exists in an E configuration with respect to the C=N double bond. The benzene rings are almost coplanar, making a dihedral angle of 2.82 (6). The sulfonamide group is twisted away from the attached phenyl ring with an N—S—C—C torsion angle of 64.84 (11)°. An intra­molecular O—H⋯N hydrogen bond stabilizes the mol­ecule, generating an S(6) ring motif. In the crystal, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network.
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spelling pubmed-29831682010-12-30 4-[(2-Hy­droxy-5-nitro­benzyl­idene)amino]­benzene­sulfonamide Tan, Yi-Han Teoh, Siang Guan Loh, Wan-Sin Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(13)H(11)N(3)O(5)S, exists in an E configuration with respect to the C=N double bond. The benzene rings are almost coplanar, making a dihedral angle of 2.82 (6). The sulfonamide group is twisted away from the attached phenyl ring with an N—S—C—C torsion angle of 64.84 (11)°. An intra­molecular O—H⋯N hydrogen bond stabilizes the mol­ecule, generating an S(6) ring motif. In the crystal, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983168/ /pubmed/21587586 http://dx.doi.org/10.1107/S1600536810036949 Text en © Tan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tan, Yi-Han
Teoh, Siang Guan
Loh, Wan-Sin
Fun, Hoong-Kun
4-[(2-Hy­droxy-5-nitro­benzyl­idene)amino]­benzene­sulfonamide
title 4-[(2-Hy­droxy-5-nitro­benzyl­idene)amino]­benzene­sulfonamide
title_full 4-[(2-Hy­droxy-5-nitro­benzyl­idene)amino]­benzene­sulfonamide
title_fullStr 4-[(2-Hy­droxy-5-nitro­benzyl­idene)amino]­benzene­sulfonamide
title_full_unstemmed 4-[(2-Hy­droxy-5-nitro­benzyl­idene)amino]­benzene­sulfonamide
title_short 4-[(2-Hy­droxy-5-nitro­benzyl­idene)amino]­benzene­sulfonamide
title_sort 4-[(2-hy­droxy-5-nitro­benzyl­idene)amino]­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983168/
https://www.ncbi.nlm.nih.gov/pubmed/21587586
http://dx.doi.org/10.1107/S1600536810036949
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AT funhoongkun 42hydroxy5nitrobenzylideneaminobenzenesulfonamide

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