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catena-Poly[[[diaquacadmium(II)]-bis[μ-3,5-bis(isonicotinamido)benzoato]] tetrahydrate]
The title compound, {[Cd(C(19)H(13)N(4)O(4))(2)(H(2)O)(2)]·4H(2)O}(n) or {[Cd(BBA)(2)(H(2)O)(2)]·4H(2)O}(n), where BBA is 3,5-bis(isonicotinamido)benzoate, is isotypic with its Mn isologue [Chen et al. (2009 ▶). J. Coord. Chem. 62, 2421–2428]. The cation sits on a twofold axis and is six-coordin...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983169/ https://www.ncbi.nlm.nih.gov/pubmed/21587402 http://dx.doi.org/10.1107/S1600536810036147 |
| _version_ | 1782191817017524224 |
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| author | Chen, Man-Sheng Deng, Yi-Fang Zhang, Chun-Hua Kuang, Dai-Zhi |
| author_facet | Chen, Man-Sheng Deng, Yi-Fang Zhang, Chun-Hua Kuang, Dai-Zhi |
| author_sort | Chen, Man-Sheng |
| collection | PubMed |
| description | The title compound, {[Cd(C(19)H(13)N(4)O(4))(2)(H(2)O)(2)]·4H(2)O}(n) or {[Cd(BBA)(2)(H(2)O)(2)]·4H(2)O}(n), where BBA is 3,5-bis(isonicotinamido)benzoate, is isotypic with its Mn isologue [Chen et al. (2009 ▶). J. Coord. Chem. 62, 2421–2428]. The cation sits on a twofold axis and is six-coordinated in a slightly distorted octahedral geometry; the polyhedra are linked into zigzag chains, which are further connected by N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds as well as π–π interactions [centroid-centroid distance of 3.639 (2) Å], giving a three-dimensional supramolecular framework. |
| format | Text |
| id | pubmed-2983169 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29831692010-12-30 catena-Poly[[[diaquacadmium(II)]-bis[μ-3,5-bis(isonicotinamido)benzoato]] tetrahydrate] Chen, Man-Sheng Deng, Yi-Fang Zhang, Chun-Hua Kuang, Dai-Zhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Cd(C(19)H(13)N(4)O(4))(2)(H(2)O)(2)]·4H(2)O}(n) or {[Cd(BBA)(2)(H(2)O)(2)]·4H(2)O}(n), where BBA is 3,5-bis(isonicotinamido)benzoate, is isotypic with its Mn isologue [Chen et al. (2009 ▶). J. Coord. Chem. 62, 2421–2428]. The cation sits on a twofold axis and is six-coordinated in a slightly distorted octahedral geometry; the polyhedra are linked into zigzag chains, which are further connected by N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds as well as π–π interactions [centroid-centroid distance of 3.639 (2) Å], giving a three-dimensional supramolecular framework. International Union of Crystallography 2010-09-11 /pmc/articles/PMC2983169/ /pubmed/21587402 http://dx.doi.org/10.1107/S1600536810036147 Text en © Chen et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Man-Sheng Deng, Yi-Fang Zhang, Chun-Hua Kuang, Dai-Zhi catena-Poly[[[diaquacadmium(II)]-bis[μ-3,5-bis(isonicotinamido)benzoato]] tetrahydrate] |
| title |
catena-Poly[[[diaquacadmium(II)]-bis[μ-3,5-bis(isonicotinamido)benzoato]] tetrahydrate] |
| title_full |
catena-Poly[[[diaquacadmium(II)]-bis[μ-3,5-bis(isonicotinamido)benzoato]] tetrahydrate] |
| title_fullStr |
catena-Poly[[[diaquacadmium(II)]-bis[μ-3,5-bis(isonicotinamido)benzoato]] tetrahydrate] |
| title_full_unstemmed |
catena-Poly[[[diaquacadmium(II)]-bis[μ-3,5-bis(isonicotinamido)benzoato]] tetrahydrate] |
| title_short |
catena-Poly[[[diaquacadmium(II)]-bis[μ-3,5-bis(isonicotinamido)benzoato]] tetrahydrate] |
| title_sort | catena-poly[[[diaquacadmium(ii)]-bis[μ-3,5-bis(isonicotinamido)benzoato]] tetrahydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983169/ https://www.ncbi.nlm.nih.gov/pubmed/21587402 http://dx.doi.org/10.1107/S1600536810036147 |
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