Cargando…
2-Phenylacetic acid–(E,E)-4,4’-(hydrazinediylidene)dipyridine (2/1)
The asymmetric unit of the title co-crystal, C(12)H(10)N(4)·2C(8)H(8)O(2), comprises a single molecule of 2-phenylacetic acid and half a molecule of 4-pyridinealdazine as this is situated about a centre of inversion. Molecules are connected into a three component aggregate via O—H⋯N hydrogen bo...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983171/ https://www.ncbi.nlm.nih.gov/pubmed/21587602 http://dx.doi.org/10.1107/S1600536810037694 |
Sumario: | The asymmetric unit of the title co-crystal, C(12)H(10)N(4)·2C(8)H(8)O(2), comprises a single molecule of 2-phenylacetic acid and half a molecule of 4-pyridinealdazine as this is situated about a centre of inversion. Molecules are connected into a three component aggregate via O—H⋯N hydrogen bonds. As the carboxylic acid group is almost normal to the plane through the benzene ring to which it is attached [C—C—C—C = 93.7 (3) °], and the 4-pyridinealdazine molecule is planar (r.m.s. deviation of the 16 non-H atoms = 0.010 Å), the overall shape of the aggregate is that of an extended chair. In the crystal packing, layers of three component aggregates stack along the c axis. |
---|