catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-malonato-κ(4) O (1),O (1′):O (3),O (3′)]

In the title compound, [Co(C(3)H(2)O(4))(C(14)H(12)N(2))](n), the Co(II) ion is in a distorted octa­hedral coordination being chelated by a 2,9-dimethyl-1,10-phenanthroline mol­ecule (dmphen) and two carboxyl­ate groups of two malonate ligands The malonate ligand acts in a bridging mode, forming coo...

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Detalles Bibliográficos
Autores principales: Qiu, Ling-Feng, Zhou, Bai-Lu, Xu, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983174/
https://www.ncbi.nlm.nih.gov/pubmed/21587459
http://dx.doi.org/10.1107/S1600536810038043
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author Qiu, Ling-Feng
Zhou, Bai-Lu
Xu, Wei
author_facet Qiu, Ling-Feng
Zhou, Bai-Lu
Xu, Wei
author_sort Qiu, Ling-Feng
collection PubMed
description In the title compound, [Co(C(3)H(2)O(4))(C(14)H(12)N(2))](n), the Co(II) ion is in a distorted octa­hedral coordination being chelated by a 2,9-dimethyl-1,10-phenanthroline mol­ecule (dmphen) and two carboxyl­ate groups of two malonate ligands The malonate ligand acts in a bridging mode, forming coordination chains along [100]. π–π stacking inter­actions between dmphen ligands [inter­planar distances = 3.414 (4) and 3.447 (4) Å] organize the coordination polymers into supra­molecular double chains.
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spelling pubmed-29831742010-12-30 catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-malonato-κ(4) O (1),O (1′):O (3),O (3′)] Qiu, Ling-Feng Zhou, Bai-Lu Xu, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(3)H(2)O(4))(C(14)H(12)N(2))](n), the Co(II) ion is in a distorted octa­hedral coordination being chelated by a 2,9-dimethyl-1,10-phenanthroline mol­ecule (dmphen) and two carboxyl­ate groups of two malonate ligands The malonate ligand acts in a bridging mode, forming coordination chains along [100]. π–π stacking inter­actions between dmphen ligands [inter­planar distances = 3.414 (4) and 3.447 (4) Å] organize the coordination polymers into supra­molecular double chains. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983174/ /pubmed/21587459 http://dx.doi.org/10.1107/S1600536810038043 Text en © Qiu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Qiu, Ling-Feng
Zhou, Bai-Lu
Xu, Wei
catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-malonato-κ(4) O (1),O (1′):O (3),O (3′)]
title catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-malonato-κ(4) O (1),O (1′):O (3),O (3′)]
title_full catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-malonato-κ(4) O (1),O (1′):O (3),O (3′)]
title_fullStr catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-malonato-κ(4) O (1),O (1′):O (3),O (3′)]
title_full_unstemmed catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-malonato-κ(4) O (1),O (1′):O (3),O (3′)]
title_short catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-malonato-κ(4) O (1),O (1′):O (3),O (3′)]
title_sort catena-poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2) n,n′)cobalt(ii)]-μ-malonato-κ(4) o (1),o (1′):o (3),o (3′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983174/
https://www.ncbi.nlm.nih.gov/pubmed/21587459
http://dx.doi.org/10.1107/S1600536810038043
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