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(μ-2′,6′-Dicarboxybiphenyl-2,6-dicarboxylato)bis[(1,10-phenanthroline)silver(I)]
In the dimeric title complex, [Ag(2)(C(16)H(8)O(8))(C(12)H(8)N(2))(2)] or [Ag(2)(H(2)bta)(phen)(2)] (H(4)bta = biphenyl-2,2′,6,6′-tetracarboxylic acid, phen = 1,10-phenanthroline), each Ag(I) ion displays an approximatively planar-trigonal geometry, being surrounded by one chelating phen ligand...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983175/ https://www.ncbi.nlm.nih.gov/pubmed/21587461 http://dx.doi.org/10.1107/S1600536810037700 |
Sumario: | In the dimeric title complex, [Ag(2)(C(16)H(8)O(8))(C(12)H(8)N(2))(2)] or [Ag(2)(H(2)bta)(phen)(2)] (H(4)bta = biphenyl-2,2′,6,6′-tetracarboxylic acid, phen = 1,10-phenanthroline), each Ag(I) ion displays an approximatively planar-trigonal geometry, being surrounded by one chelating phen ligand and one carboxylate O atom from an H(2)bta ligand. Owing to the the presence of crystallographic twofold rotation axes, the four C atoms bisecting the H~2~bta ligand are located on a special position. Each H(2)bta ligand acts as a bis-monodentate ligand, ligating two Ag(I) ions into a dimeric compound. Intermolecular O—H⋯O interactions are observed in the crystal structure. |
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