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(μ-2′,6′-Dicarboxy­biphenyl-2,6-dicar­boxylato)bis[(1,10-phenanthroline)silver(I)]

In the dimeric title complex, [Ag(2)(C(16)H(8)O(8))(C(12)H(8)N(2))(2)] or [Ag(2)(H(2)bta)(phen)(2)] (H(4)bta = biphenyl-2,2′,6,6′-tetra­carb­ox­y­lic acid, phen = 1,10-phenanthroline), each Ag(I) ion displays an approximatively planar-trigonal geometry, being surrounded by one chelating phen ligand...

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Detalles Bibliográficos
Autores principales: Cheng, Lin, Wang, Jian-Quan, Zhang, Li-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983175/
https://www.ncbi.nlm.nih.gov/pubmed/21587461
http://dx.doi.org/10.1107/S1600536810037700
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author Cheng, Lin
Wang, Jian-Quan
Zhang, Li-Min
author_facet Cheng, Lin
Wang, Jian-Quan
Zhang, Li-Min
author_sort Cheng, Lin
collection PubMed
description In the dimeric title complex, [Ag(2)(C(16)H(8)O(8))(C(12)H(8)N(2))(2)] or [Ag(2)(H(2)bta)(phen)(2)] (H(4)bta = biphenyl-2,2′,6,6′-tetra­carb­ox­y­lic acid, phen = 1,10-phenanthroline), each Ag(I) ion displays an approximatively planar-trigonal geometry, being surrounded by one chelating phen ligand and one carboxyl­ate O atom from an H(2)bta ligand. Owing to the the presence of crystallographic twofold rotation axes, the four C atoms bisecting the H~2~bta ligand are located on a special position. Each H(2)bta ligand acts as a bis-monodentate ligand, ligating two Ag(I) ions into a dimeric compound. Inter­molecular O—H⋯O inter­actions are observed in the crystal structure.
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spelling pubmed-29831752010-12-30 (μ-2′,6′-Dicarboxy­biphenyl-2,6-dicar­boxylato)bis[(1,10-phenanthroline)silver(I)] Cheng, Lin Wang, Jian-Quan Zhang, Li-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the dimeric title complex, [Ag(2)(C(16)H(8)O(8))(C(12)H(8)N(2))(2)] or [Ag(2)(H(2)bta)(phen)(2)] (H(4)bta = biphenyl-2,2′,6,6′-tetra­carb­ox­y­lic acid, phen = 1,10-phenanthroline), each Ag(I) ion displays an approximatively planar-trigonal geometry, being surrounded by one chelating phen ligand and one carboxyl­ate O atom from an H(2)bta ligand. Owing to the the presence of crystallographic twofold rotation axes, the four C atoms bisecting the H~2~bta ligand are located on a special position. Each H(2)bta ligand acts as a bis-monodentate ligand, ligating two Ag(I) ions into a dimeric compound. Inter­molecular O—H⋯O inter­actions are observed in the crystal structure. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983175/ /pubmed/21587461 http://dx.doi.org/10.1107/S1600536810037700 Text en © Cheng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cheng, Lin
Wang, Jian-Quan
Zhang, Li-Min
(μ-2′,6′-Dicarboxy­biphenyl-2,6-dicar­boxylato)bis[(1,10-phenanthroline)silver(I)]
title (μ-2′,6′-Dicarboxy­biphenyl-2,6-dicar­boxylato)bis[(1,10-phenanthroline)silver(I)]
title_full (μ-2′,6′-Dicarboxy­biphenyl-2,6-dicar­boxylato)bis[(1,10-phenanthroline)silver(I)]
title_fullStr (μ-2′,6′-Dicarboxy­biphenyl-2,6-dicar­boxylato)bis[(1,10-phenanthroline)silver(I)]
title_full_unstemmed (μ-2′,6′-Dicarboxy­biphenyl-2,6-dicar­boxylato)bis[(1,10-phenanthroline)silver(I)]
title_short (μ-2′,6′-Dicarboxy­biphenyl-2,6-dicar­boxylato)bis[(1,10-phenanthroline)silver(I)]
title_sort (μ-2′,6′-dicarboxy­biphenyl-2,6-dicar­boxylato)bis[(1,10-phenanthroline)silver(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983175/
https://www.ncbi.nlm.nih.gov/pubmed/21587461
http://dx.doi.org/10.1107/S1600536810037700
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