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(μ-2′,6′-Dicarboxybiphenyl-2,6-dicarboxylato)bis[(1,10-phenanthroline)silver(I)]
In the dimeric title complex, [Ag(2)(C(16)H(8)O(8))(C(12)H(8)N(2))(2)] or [Ag(2)(H(2)bta)(phen)(2)] (H(4)bta = biphenyl-2,2′,6,6′-tetracarboxylic acid, phen = 1,10-phenanthroline), each Ag(I) ion displays an approximatively planar-trigonal geometry, being surrounded by one chelating phen ligand...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983175/ https://www.ncbi.nlm.nih.gov/pubmed/21587461 http://dx.doi.org/10.1107/S1600536810037700 |
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author | Cheng, Lin Wang, Jian-Quan Zhang, Li-Min |
author_facet | Cheng, Lin Wang, Jian-Quan Zhang, Li-Min |
author_sort | Cheng, Lin |
collection | PubMed |
description | In the dimeric title complex, [Ag(2)(C(16)H(8)O(8))(C(12)H(8)N(2))(2)] or [Ag(2)(H(2)bta)(phen)(2)] (H(4)bta = biphenyl-2,2′,6,6′-tetracarboxylic acid, phen = 1,10-phenanthroline), each Ag(I) ion displays an approximatively planar-trigonal geometry, being surrounded by one chelating phen ligand and one carboxylate O atom from an H(2)bta ligand. Owing to the the presence of crystallographic twofold rotation axes, the four C atoms bisecting the H~2~bta ligand are located on a special position. Each H(2)bta ligand acts as a bis-monodentate ligand, ligating two Ag(I) ions into a dimeric compound. Intermolecular O—H⋯O interactions are observed in the crystal structure. |
format | Text |
id | pubmed-2983175 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29831752010-12-30 (μ-2′,6′-Dicarboxybiphenyl-2,6-dicarboxylato)bis[(1,10-phenanthroline)silver(I)] Cheng, Lin Wang, Jian-Quan Zhang, Li-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the dimeric title complex, [Ag(2)(C(16)H(8)O(8))(C(12)H(8)N(2))(2)] or [Ag(2)(H(2)bta)(phen)(2)] (H(4)bta = biphenyl-2,2′,6,6′-tetracarboxylic acid, phen = 1,10-phenanthroline), each Ag(I) ion displays an approximatively planar-trigonal geometry, being surrounded by one chelating phen ligand and one carboxylate O atom from an H(2)bta ligand. Owing to the the presence of crystallographic twofold rotation axes, the four C atoms bisecting the H~2~bta ligand are located on a special position. Each H(2)bta ligand acts as a bis-monodentate ligand, ligating two Ag(I) ions into a dimeric compound. Intermolecular O—H⋯O interactions are observed in the crystal structure. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983175/ /pubmed/21587461 http://dx.doi.org/10.1107/S1600536810037700 Text en © Cheng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Cheng, Lin Wang, Jian-Quan Zhang, Li-Min (μ-2′,6′-Dicarboxybiphenyl-2,6-dicarboxylato)bis[(1,10-phenanthroline)silver(I)] |
title | (μ-2′,6′-Dicarboxybiphenyl-2,6-dicarboxylato)bis[(1,10-phenanthroline)silver(I)] |
title_full | (μ-2′,6′-Dicarboxybiphenyl-2,6-dicarboxylato)bis[(1,10-phenanthroline)silver(I)] |
title_fullStr | (μ-2′,6′-Dicarboxybiphenyl-2,6-dicarboxylato)bis[(1,10-phenanthroline)silver(I)] |
title_full_unstemmed | (μ-2′,6′-Dicarboxybiphenyl-2,6-dicarboxylato)bis[(1,10-phenanthroline)silver(I)] |
title_short | (μ-2′,6′-Dicarboxybiphenyl-2,6-dicarboxylato)bis[(1,10-phenanthroline)silver(I)] |
title_sort | (μ-2′,6′-dicarboxybiphenyl-2,6-dicarboxylato)bis[(1,10-phenanthroline)silver(i)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983175/ https://www.ncbi.nlm.nih.gov/pubmed/21587461 http://dx.doi.org/10.1107/S1600536810037700 |
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