catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]

Hexa­methyl­phospho­ramide (hmp), tetra­thio­tungstate, silver sulfide and dysprosium nitrate were self-assembled, forming an anionic [AgWS(4)](n)(n) (−) chain in the title compound, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms f...

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Detalles Bibliográficos
Autores principales: Wei, Hongyang, Zhang, Jinfang, Zhang, Chi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983176/
https://www.ncbi.nlm.nih.gov/pubmed/21587356
http://dx.doi.org/10.1107/S1600536810029235
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author Wei, Hongyang
Zhang, Jinfang
Zhang, Chi
author_facet Wei, Hongyang
Zhang, Jinfang
Zhang, Chi
author_sort Wei, Hongyang
collection PubMed
description Hexa­methyl­phospho­ramide (hmp), tetra­thio­tungstate, silver sulfide and dysprosium nitrate were self-assembled, forming an anionic [AgWS(4)](n)(n) (−) chain in the title compound, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from two didentate nitrate and four hmp ligands, giving rise to a distorted square anti­prismatic structure. Together with the two nitrate ligands, the cation is univalent, which leads to the anionic chain having a [WS(4)Ag] repeat unit. The polymeric anionic chain, with W—Ag—W and Ag—W—Ag angles 161.16 (2) and 153.606 (11)°, respectively, presents a distorted linear configuration. The title compound is isotypic with other rare earth complexes.
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spelling pubmed-29831762010-12-30 catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]] Wei, Hongyang Zhang, Jinfang Zhang, Chi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Hexa­methyl­phospho­ramide (hmp), tetra­thio­tungstate, silver sulfide and dysprosium nitrate were self-assembled, forming an anionic [AgWS(4)](n)(n) (−) chain in the title compound, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from two didentate nitrate and four hmp ligands, giving rise to a distorted square anti­prismatic structure. Together with the two nitrate ligands, the cation is univalent, which leads to the anionic chain having a [WS(4)Ag] repeat unit. The polymeric anionic chain, with W—Ag—W and Ag—W—Ag angles 161.16 (2) and 153.606 (11)°, respectively, presents a distorted linear configuration. The title compound is isotypic with other rare earth complexes. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983176/ /pubmed/21587356 http://dx.doi.org/10.1107/S1600536810029235 Text en © Wei et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wei, Hongyang
Zhang, Jinfang
Zhang, Chi
catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title_full catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title_fullStr catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title_full_unstemmed catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title_short catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title_sort catena-poly[[tetra­kis­(hexa­methyl­phospho­ramide-κo)bis­(nitrato-κ(2) o,o′)dysprosium(iii)] [silver(i)-di-μ-sulfido-tungstate(vi)-di-μ-sulfido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983176/
https://www.ncbi.nlm.nih.gov/pubmed/21587356
http://dx.doi.org/10.1107/S1600536810029235
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AT zhangjinfang catenapolytetrakishexamethylphosphoramidekobisnitratok2oodysprosiumiiisilveridimsulfidotungstatevidimsulfido
AT zhangchi catenapolytetrakishexamethylphosphoramidekobisnitratok2oodysprosiumiiisilveridimsulfidotungstatevidimsulfido

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