Bis[2-amino-6-methyl­pyrimidin-4(1H)-one-κ(2) N (3),O]dichloridocadmium(II)

In the title compound, [CdCl(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is six-coordinated by two heterocyclic N atoms [Cd—N = 2.261 (2) and 2.286 (2) Å] and two O atoms [Cd—O = 2.624 (2) and 2.692 (2) Å] from two bidentate chelate 2-amino-6-methyl­pyrimidin-4(1H)-one ligands and two chloride ions [Cd—C...

Descripción completa

Detalles Bibliográficos
Autores principales: Kaabi, Kamel, El Glaoui, Meher, Pereira Silva, P. S, Ramos Silva, M., Ben Nasr, Cherif
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983177/
https://www.ncbi.nlm.nih.gov/pubmed/21587381
http://dx.doi.org/10.1107/S1600536810035051
_version_ 1782191818972069888
author Kaabi, Kamel
El Glaoui, Meher
Pereira Silva, P. S
Ramos Silva, M.
Ben Nasr, Cherif
author_facet Kaabi, Kamel
El Glaoui, Meher
Pereira Silva, P. S
Ramos Silva, M.
Ben Nasr, Cherif
author_sort Kaabi, Kamel
collection PubMed
description In the title compound, [CdCl(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is six-coordinated by two heterocyclic N atoms [Cd—N = 2.261 (2) and 2.286 (2) Å] and two O atoms [Cd—O = 2.624 (2) and 2.692 (2) Å] from two bidentate chelate 2-amino-6-methyl­pyrimidin-4(1H)-one ligands and two chloride ions [Cd—Cl = 2.4674 (6) and 2.4893 (7) Å]. The crystal packing is characterized by an open-framework architecture with the crystal packing stabilized by inter­molecular N—H⋯Cl and N—H⋯O hydrogen bonds.
format Text
id pubmed-2983177
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29831772010-12-30 Bis[2-amino-6-methyl­pyrimidin-4(1H)-one-κ(2) N (3),O]dichloridocadmium(II) Kaabi, Kamel El Glaoui, Meher Pereira Silva, P. S Ramos Silva, M. Ben Nasr, Cherif Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdCl(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is six-coordinated by two heterocyclic N atoms [Cd—N = 2.261 (2) and 2.286 (2) Å] and two O atoms [Cd—O = 2.624 (2) and 2.692 (2) Å] from two bidentate chelate 2-amino-6-methyl­pyrimidin-4(1H)-one ligands and two chloride ions [Cd—Cl = 2.4674 (6) and 2.4893 (7) Å]. The crystal packing is characterized by an open-framework architecture with the crystal packing stabilized by inter­molecular N—H⋯Cl and N—H⋯O hydrogen bonds. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983177/ /pubmed/21587381 http://dx.doi.org/10.1107/S1600536810035051 Text en © Kaabi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kaabi, Kamel
El Glaoui, Meher
Pereira Silva, P. S
Ramos Silva, M.
Ben Nasr, Cherif
Bis[2-amino-6-methyl­pyrimidin-4(1H)-one-κ(2) N (3),O]dichloridocadmium(II)
title Bis[2-amino-6-methyl­pyrimidin-4(1H)-one-κ(2) N (3),O]dichloridocadmium(II)
title_full Bis[2-amino-6-methyl­pyrimidin-4(1H)-one-κ(2) N (3),O]dichloridocadmium(II)
title_fullStr Bis[2-amino-6-methyl­pyrimidin-4(1H)-one-κ(2) N (3),O]dichloridocadmium(II)
title_full_unstemmed Bis[2-amino-6-methyl­pyrimidin-4(1H)-one-κ(2) N (3),O]dichloridocadmium(II)
title_short Bis[2-amino-6-methyl­pyrimidin-4(1H)-one-κ(2) N (3),O]dichloridocadmium(II)
title_sort bis[2-amino-6-methyl­pyrimidin-4(1h)-one-κ(2) n (3),o]dichloridocadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983177/
https://www.ncbi.nlm.nih.gov/pubmed/21587381
http://dx.doi.org/10.1107/S1600536810035051
work_keys_str_mv AT kaabikamel bis2amino6methylpyrimidin41honek2n3odichloridocadmiumii
AT elglaouimeher bis2amino6methylpyrimidin41honek2n3odichloridocadmiumii
AT pereirasilvaps bis2amino6methylpyrimidin41honek2n3odichloridocadmiumii
AT ramossilvam bis2amino6methylpyrimidin41honek2n3odichloridocadmiumii
AT bennasrcherif bis2amino6methylpyrimidin41honek2n3odichloridocadmiumii

Ejemplares similares