Bis(pyridine-2-carbaldehyde thio­semi­carbazone)zinc(II) dinitrate dihydrate

The asymmetric unit of the title compound, [Zn(C(7)H(8)N(4)S)(2)](NO(3))(2)·2H(2)O, contains two Zn(pht)(2) cations (pht is pyridine-2-carbaldehyde thio­semicarbazone), four nitrate anions and four water mol­ecules. In the cations, each Zn(II) ion adopts a distorted octa­hedral coordination geometry...

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Detalles Bibliográficos
Autores principales: Cheng, Lin, Zhang, Li-Min, Wang, Jian-Quan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983178/
https://www.ncbi.nlm.nih.gov/pubmed/21587469
http://dx.doi.org/10.1107/S1600536810038614
Descripción
Sumario:The asymmetric unit of the title compound, [Zn(C(7)H(8)N(4)S)(2)](NO(3))(2)·2H(2)O, contains two Zn(pht)(2) cations (pht is pyridine-2-carbaldehyde thio­semicarbazone), four nitrate anions and four water mol­ecules. In the cations, each Zn(II) ion adopts a distorted octa­hedral coordination geometry, being chelated by two tridentate pht ligands. In the crystal, the cations, anions and water mol­ecules are connected via O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network.

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