Bis(pyridine-2-carbaldehyde thio­semi­carbazone)zinc(II) dinitrate dihydrate

The asymmetric unit of the title compound, [Zn(C(7)H(8)N(4)S)(2)](NO(3))(2)·2H(2)O, contains two Zn(pht)(2) cations (pht is pyridine-2-carbaldehyde thio­semicarbazone), four nitrate anions and four water mol­ecules. In the cations, each Zn(II) ion adopts a distorted octa­hedral coordination geometry...

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Detalles Bibliográficos
Autores principales: Cheng, Lin, Zhang, Li-Min, Wang, Jian-Quan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983178/
https://www.ncbi.nlm.nih.gov/pubmed/21587469
http://dx.doi.org/10.1107/S1600536810038614
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author Cheng, Lin
Zhang, Li-Min
Wang, Jian-Quan
author_facet Cheng, Lin
Zhang, Li-Min
Wang, Jian-Quan
author_sort Cheng, Lin
collection PubMed
description The asymmetric unit of the title compound, [Zn(C(7)H(8)N(4)S)(2)](NO(3))(2)·2H(2)O, contains two Zn(pht)(2) cations (pht is pyridine-2-carbaldehyde thio­semicarbazone), four nitrate anions and four water mol­ecules. In the cations, each Zn(II) ion adopts a distorted octa­hedral coordination geometry, being chelated by two tridentate pht ligands. In the crystal, the cations, anions and water mol­ecules are connected via O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network.
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spelling pubmed-29831782010-12-30 Bis(pyridine-2-carbaldehyde thio­semi­carbazone)zinc(II) dinitrate dihydrate Cheng, Lin Zhang, Li-Min Wang, Jian-Quan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(C(7)H(8)N(4)S)(2)](NO(3))(2)·2H(2)O, contains two Zn(pht)(2) cations (pht is pyridine-2-carbaldehyde thio­semicarbazone), four nitrate anions and four water mol­ecules. In the cations, each Zn(II) ion adopts a distorted octa­hedral coordination geometry, being chelated by two tridentate pht ligands. In the crystal, the cations, anions and water mol­ecules are connected via O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983178/ /pubmed/21587469 http://dx.doi.org/10.1107/S1600536810038614 Text en © Cheng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cheng, Lin
Zhang, Li-Min
Wang, Jian-Quan
Bis(pyridine-2-carbaldehyde thio­semi­carbazone)zinc(II) dinitrate dihydrate
title Bis(pyridine-2-carbaldehyde thio­semi­carbazone)zinc(II) dinitrate dihydrate
title_full Bis(pyridine-2-carbaldehyde thio­semi­carbazone)zinc(II) dinitrate dihydrate
title_fullStr Bis(pyridine-2-carbaldehyde thio­semi­carbazone)zinc(II) dinitrate dihydrate
title_full_unstemmed Bis(pyridine-2-carbaldehyde thio­semi­carbazone)zinc(II) dinitrate dihydrate
title_short Bis(pyridine-2-carbaldehyde thio­semi­carbazone)zinc(II) dinitrate dihydrate
title_sort bis(pyridine-2-carbaldehyde thio­semi­carbazone)zinc(ii) dinitrate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983178/
https://www.ncbi.nlm.nih.gov/pubmed/21587469
http://dx.doi.org/10.1107/S1600536810038614
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AT wangjianquan bispyridine2carbaldehydethiosemicarbazonezinciidinitratedihydrate

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